Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Andrea Causero"'
Publikováno v:
Industrial & Engineering Chemistry Research. 59:15464-15477
(+)-Limonene has been used as starting material for the synthesis of eco-friendly building blocks for new bio-based polymers. A very effective protocol has been developed for the solvent-free Rh-ca...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5bf8a526050abeaf581561876896b2fe
https://doi.org/10.1021/acs.iecr.0c02998
https://doi.org/10.1021/acs.iecr.0c02998
The first “naked” (Lewis base‐free) cationic Ca amidinate complex [tBuAmDIPPCa(C6H6)]+[B(C6F5)4]– was prepared in 62 % yield {tBuAmDIPP = tBuC(N–DIPP)2; DIPP = 2,6‐diisopropylphenyl} by reaction of [tBuAmDIPPCaH]2 with [Ph3C]+[B(C6F5)4]
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::057d2e7b588e70a5bf60ff9c773c0658
https://opus4.kobv.de/opus4-fau/frontdoor/index/index/docId/15180
https://opus4.kobv.de/opus4-fau/frontdoor/index/index/docId/15180
Publikováno v:
Angewandte Chemie. 129:7010-7014
An anionic N-heterocyclic olefin ligand was serendipitously obtained by reaction of an amidinate calcium hydride complex with 1,3-dimethyl-2-methyleneimidazole (NHO). Instead of anticipated addition to the polarized C=CH2 bond to form an unstabilized
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::75b5216eb52f4e5e88af42e9d1b13e2a
https://doi.org/10.1002/ange.201703037
https://doi.org/10.1002/ange.201703037
Publikováno v:
Dalton Transactions. 46:1822-1831
A series of (DIPPnacnac)CaN(SiMe3)2·S complexes (DIPPnacnac = HC[C(Me)N(2,6-iPr-C6H3)]2; S = solvent) could be obtained by the addition of S = THF, DME or N-Me-morpholine (Morph) to (DIPPnacnac)CaN(SiMe3)2·OEt2 or (DIPPnacnac)CaN(SiMe3)2. Crystal s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ad6cd3700e8b23efa46a92e1bf5aedce
https://doi.org/10.1039/c6dt04659b
https://doi.org/10.1039/c6dt04659b
Publikováno v:
Chemical Communications. 53:10386-10389
Addition of a calcium hydride complex to diphenylacetylene gave a complex in which the stilbene dianion symmetrically bridges two Ca2+ ions. DFT calculations discuss the effect of the metal stilbene coordination. The stilbene complex reacts as a base
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::92d5fb04bd00f2606f0fa718b9eda744
https://doi.org/10.1039/c7cc05792j
https://doi.org/10.1039/c7cc05792j
Autor:
Andrea Causero, Christian Färber, Harmen S. Zijlstra, Jürgen Pahl, Sjoerd Harder, Gerd Ballmann
Publikováno v:
Organometallics. 35:3350-3360
A range of symmetric amidinate ligands RAmAr (R is backbone substituent, Ar is N substituent) have been investigated for their ability to stabilize calcium hydride complexes of the type RAmArCaH. It was found that the precursors of the type RAmArCaN(
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::abf6eadd885a522effbc9f87f78b69a0
https://doi.org/10.1021/acs.organomet.6b00566
https://doi.org/10.1021/acs.organomet.6b00566