Zobrazeno 1 - 10
of 57
pro vyhledávání: '"Andre Clayborne"'
Autor:
Nia Pollard, Andre Clayborne
Atomically precise nanochemistry relies on understanding the structure and properties of clusters with precise details at the atomic level. Here, we report on the effects of changing the atomic composition of the superatomic gold-gallium cluster [(PL
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::45e54a1e6078cd8f353dd345f2fc90b5
https://doi.org/10.21203/rs.3.rs-2231969/v1
https://doi.org/10.21203/rs.3.rs-2231969/v1
Autor:
Liang Qiao, Nia Pollard, Ravithree Senanayake, Zhi Yang, Minjung Kim, Arzeena Ali, Minh Tam Hoang, Nan Yao, Yimo Han, Rigoberto Hernandez, Andre Clayborne, Matthew Jones
Seed-mediated synthesis strategies, in which small nanoparticle precursors are added to a growth solution to initiate heterogeneous nucleation, are among the most prevalent, simple, and productive methodologies for generating well-defined colloidal a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::44d175735e06322a3a42618ed5cc12fa
https://doi.org/10.26434/chemrxiv-2022-r18wr
https://doi.org/10.26434/chemrxiv-2022-r18wr
Autor:
Andreas Schnepf, Adebola Adeagbo, Claudio Schrenk, Nia Pollard, Florian Fetzer, Andre Clayborne
Publikováno v:
Chemical Communications. 57:3551-3554
The low valent gallium(I) compound GaCp was primarily used in gold cluster chemistry to synthesize the superatomic cluster [(PPh3)8Au9GaCl2]2+, complementing the borane-dominated set of reducing agents in gold chemistry, opening a whole new field for
Publikováno v:
The Journal of Physical Chemistry A. 124:6504-6510
Atomically precise copper clusters (APC) have attracted attention for their promise in sensing, water remediation, and electrochemical technologies. However, smaller-sized APCs and the evolution of their properties as a function of size and compositi
Autor:
Nia Pollard, Sebastian Kenzler, Claudio Schrenk, Florian Fetzer, Andreas Schnepf, Andre Clayborne, Andrew R. Frojd
Publikováno v:
Angewandte Chemie International Edition. 58:5902-5905
Three multi-shell metalloid gold clusters of the composition Au32 (R3 P)12 Cl8 (R=Et, n Pr, n Bu) were synthesized in a straightforward fashion by reducing R3 PAuCl with NaBH4 in ethanol. The Au32 core comprises two shells, with the inner one constit
Autor:
Sebastian Kenzler, Andreas Schnepf, Florian Fetzer, Nia Pollard, Andre Clayborne, Claudio Schrenk, Andrew R. Frojd
Publikováno v:
Angewandte Chemie. 131:5962-5966
Autor:
Xinlei Liu, Xiaohui Gao, Guanghua Ye, Zhihua Zhuang, Xiaokun Li, Wei Chen, Cheng Du, Xinggui Zhou, Dong Xiang, Andre Clayborne, Ping Li
Publikováno v:
ChemSusChem. 12:1017-1025
Carbonaceous porous structures have instigated global research interest as promising low-cost electrocatalysts for numerous energy technologies. However, the rational design principle of pore structures for activity maximization is still unclear. In
Publikováno v:
Inorganic Chemistry. 57:12603-12609
The reaction of [ZnGe18(Hyp)6] (Hyp = Si(SiMe3)3) with Pt(PPh3)4 gives the neutral polynuclear complex of Ge9(Hyp)3 units [HypZn–Ge9(Hyp)3–Pt–Ge9(Hyp)3–ZnHyp], 1. Within 1, the central Pt atom is b...
Publikováno v:
Nano Energy. 50:316-322
The search for highly active catalysts with low-Pt content to advance the commercialization of fuel cells is continuing to receive ample attention. Herein, we report that by doping a single Pt atom into Au25 to form Pt1Au24 nanoclusters, the electroc
Autor:
Hannu Häkkinen, Andreas Schnepf, Claudio Schrenk, Sebastian Kenzler, Andrew R. Frojd, Andre Clayborne
Publikováno v:
Chemical Communications. 54:248-251
Reducing (Ph3P)AuSC(SiMe3)3 with L-Selectride® gives the medium-sized metalloid gold cluster Au70S20(PPh3)12. Computational studies show that the phosphine bound Au-atoms not only stabilize the electronic structure of Au70S20(PPh3)12, but also behav