Importance of Relativistic Effects for Carbon as an NMR Reporter Nucleus in Carbide-Bridged [RuCPt] Complexes

Autor: Anders Reinholdt, Iben Glent-Madsen, Stephan P. A. Sauer, Jesper Bendix

Publikováno v: Organometallics. 40:1443-1453

Carbide-bridged ruthenium platinum complexes of the general formula trans-(Cy3P)2Cl2Ru≡C–PtCl2-L show a remarkable ability to probe the ligand donor strength of the ligand L. An experimentally obse...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ec3e2718c1922bc7f0606d8d0b162cdf
https://doi.org/10.1021/acs.organomet.1c00079

A Mononuclear and High-Spin Tetrahedral TiII Complex

Autor: Karsten Meyer, Ida M. DiMucci, Joshua Telser, Daniel Pividori, Andrew Ozarowski, Mehrafshan G. Jafari, Patrick J. Carroll, J. Krzystek, Michael R. Gau, Daniel J. Mindiola, Alexander L Laughlin, Samantha N. MacMillan, Kyle M. Lancaster, Anders Reinholdt

Publikováno v: Inorg Chem

[Image: see text] A high-spin, mononuclear Ti(II) complex, [(Tp(tBu,Me))TiCl] [Tp(tBu,Me–) = hydridotris(3-tert-butyl-5-methylpyrazol-1-yl)borate], confined to a tetrahedral ligand-field environment, has been prepared by reduction of the precursor

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f8bcdd637e9a1132820f2b6baa7cfe3
https://doi.org/10.1021/acs.inorgchem.0c02586

Transition Metal Carbide Complexes

Autor: Jesper Bendix, Anders Reinholdt

Publikováno v: Chemical reviews. 122(1)

Carbide complexes remain a rare class of molecules. Their paucity does not reflect exceptional instability but is rather due to the generally narrow scope of synthetic procedures for constructing carbide complexes. The preparation of carbide complexe

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https://pubmed.ncbi.nlm.nih.gov/34797626

Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet† †Electronic supplementary information (ESI) available: Full experimental details and additional data for all the characterizations presented in the main text. Crystallographic data (including structure factors) for 1ΔΔ and 1ΛΛ have been deposited with the Cambridge Crystallographic Data Centre (CCDC 1839660-1839661, respectively). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc04917c

Autor: Euan K. Brechin, Stergios Piligkos, Peter W. Thulstrup, Rikke M. Gelardi, Andrei Rogalev, Wolfgang Wernsdorfer, Dmitri Mitcov, Marcel Ceccato, Anders Holmen Pedersen, Anders Reinholdt, Tue Hassenkam, Fabrice Wilhelm, Andreas Konstantatos, Morten Gotthold Vinum, Mikkel Sørensen

Publikováno v: Chemical Science
Mitcov, D, Pedersen, A H, Ceccato, M, Gelardi, R M, Hassenkam, T, Konstantatos, A, Reinholdt, A, Sorensen, M A, Thulstrup, P W, Vinum, M G, Wilhelm, F, Rogalev, A, Wernsdorfer, W, Brechin, E K & Piligkos, S 2019, ' Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet ', Chemical Science, vol. 10, no. 10, pp. 3065-3073 . https://doi.org/10.1039/C8SC04917C
Mitcov, D, Pedersen, A H, Ceccato, M, Gelardi, R M, Hassenkam, T, Konstantatos, A, Reinholdt, A, Sørensen, M A, Thulstrup, P W, Vinum, M G, Wilhelm, F, Rogalev, A, Wernsdorfer, W, Brechin, E K & Piligkos, S 2019, ' Molecular multifunctionality preservation upon surface deposition for a chiral single-molecule magnet ', Chemical Science, vol. 10, no. 10, pp. 3065-3073 . https://doi.org/10.1039/c8sc04917c
'Chemical Science ', vol: 10, pages: 3065-3073 (2019)

Simultaneous retention of SMM behaviour and of optical activity is demonstrated upon surface deposition for a chiral SMM.
The synthesis and characterization of a chiral, enneanuclear Mn(iii)-based, Single-Molecule Magnet, [Mn9O4(Me-sao)6(L)3(MeO

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2056a27c77dd2addc1f7ff68e75e0ff7
http://europepmc.org/articles/PMC6428142

Chromium(III) Complexes

Autor: Daniel J. Mindiola, Anders Reinholdt, Orion Staples

Publikováno v: Comprehensive Coordination Chemistry III ISBN: 9780081026892
Comprehensive Coordination Chemistry III

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b9d9f4de22a5d388be3d36b7fcd0f5ab
https://doi.org/10.1016/b978-0-08-102688-5.00013-1