Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Anatoly N. Nikitin"'
Publikováno v:
Polymer Chemistry. 13:3053-3062
The marked chain-length dependence of the propagation rate coefficient of long-chain radicals has been determined for methyl acrylate bulk polymerization at 25 °C through the analysis of data obtained by the PLP-SEC method applying novel approaches.
Autor:
Anatoly N. Nikitin, Anna Urbanová, Igor Lacík, Robin A. Hutchinson, Marián Sedlák, Hugo M. Vale, Ikenna H. Ezenwajiaku
Publikováno v:
Macromolecules. 54:3204-3222
The decisive role of counterions on the propagation mechanism in the radical polymerization of ionized monomers is comprehensively studied. Propagation rate coefficients, kp, were obtained for cati...
Publikováno v:
Macromolecules. 52:55-71
The factors influencing the periodic structure in molar mass distributions (MMDs) generated in pulsed-laser polymerization (PLP) experiments are investigated to extend the range of operating conditions under which radical polymerization propagation r
Autor:
Anna Urbanová, Ikenna H. Ezenwajiaku, Anatoly N. Nikitin, Marián Sedlák, Hugo M. Vale, Robin A. Hutchinson, Igor Lacík
Publikováno v:
Macromolecules. 54:7673-7674
Publikováno v:
Macromolecules. 49:9320-9335
A numerical approach has been developed to capture the inhomogeneous and nonstationary processes of pulsed laser polymerization (PLP). The new simulation tool has been applied to systematically investigate how temperature gradients that develop in th
Publikováno v:
Macromolecules. 47:8145-8153
The radical propagation kinetics of vinyl acetate (VAc) has been studied by pulsed-laser polymerization coupled with analysis of the resulting polymer molar mass distributions. The significant increase in the apparent propagation rate coefficient obs
Autor:
Christof Schütte, Maximilian E. R. Weiss, Anatoly N. Nikitin, Florian Paulus, Rainer Haag, Dirk Steinhilber
Publikováno v:
Macromolecules. 46:8458-8466
We have investigated the anionic ring-opening multibranching polymerization for hyperbranched polyglycerol using slow monomer addition at 120 °C. Different molecular masses were targeted, and the reaction mixture was probed at regular intervals for
Publikováno v:
Macromolecular Chemistry and Physics. 214:2670-2682
Publikováno v:
Macromolecular Theory and Simulations. 22:475-489
The modeling approach called “numerical fractionation” has been incorporated into a PREDICI model to simulate crosslinking copolymerization. In order to take inhomogeneities of the considered copolymerization into account, the kinetic parameters
Autor:
Anatoly N. Nikitin, Vyacheslav V. Sumin, R. N. Vasin, Petr Lukáš, Tomáš Lokajíček, I. V. Papushkin
Publikováno v:
Carbon. 49:1374-1384
The elastic properties of an extruded graphite (GR-280) used in nuclear industry have been examined. The lattice preferred orientation was determined by time-of-flight neutron diffraction that revealed weak texture with a texture index of less than 1