Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Ana M. Gallego"'
Autor:
Guillermo Marcos-Ayuso, Marconi N. Peñas-Defrutos, Ana M. Gallego, Max García-Melchor, Jesús M. Martínez-Ilarduya, Pablo Espinet
Publikováno v:
Journal of the American Chemical Society. 145:527-536
Producción Científica
The synthesis of aryl–alkynyl compounds is usually achieved via Sonogashira catalysis, but this is inefficient for fluorinated aryls. An alternative method reported by Shirakawa and Hiyama, using alkynylstannanes and he
The synthesis of aryl–alkynyl compounds is usually achieved via Sonogashira catalysis, but this is inefficient for fluorinated aryls. An alternative method reported by Shirakawa and Hiyama, using alkynylstannanes and he
Autor:
Guillermo, Marcos-Ayuso, Marconi N, Peñas-Defrutos, Ana M, Gallego, Max, García-Melchor, Jesús M, Martínez-Ilarduya, Pablo, Espinet
Publikováno v:
Journal of the American Chemical Society.
The synthesis of aryl-alkynyl compounds is usually achieved via Sonogashira catalysis, but this is inefficient for fluorinated aryls. An alternative method reported by Shirakawa and Hiyama, using alkynylstannanes and hemilabile PN ligands, works appa
Autor:
Pablo Espinet, Jesús M. Martínez-Ilarduya, Marconi N. Peñas-Defrutos, Guillermo Marcos-Ayuso, Jose M. Martín-Alvarez, Ana M. Gallego
Publikováno v:
UVaDOC. Repositorio Documental de la Universidad de Valladolid
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Producción Científica
Neutral palladium(II) complexes [Pd(Rf)X(P–L)] (Rf = 3,5-C6Cl2F3, X = Cl, I, OTf) with P–P (dppe and dppf) and P–N (PPh2(bzN)) ligands have chelated structures in the solid-state, except for P–L = dppf and X = Cl,
Neutral palladium(II) complexes [Pd(Rf)X(P–L)] (Rf = 3,5-C6Cl2F3, X = Cl, I, OTf) with P–P (dppe and dppf) and P–N (PPh2(bzN)) ligands have chelated structures in the solid-state, except for P–L = dppf and X = Cl,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0f818d92ed3f16e8cd4232cb8e6d9ac5
https://doi.org/10.1039/d0dt02335c
https://doi.org/10.1039/d0dt02335c
Autor:
Ana M Gallego
Publikováno v:
Bio-grafía, Vol 0, Iss 0 (2011)
Externí odkaz:
https://doaj.org/article/265192293ec74d40b1de8506f22342e5
Autor:
Pablo Espinet, Celeste Pérez-Briso, Ana M. Gallego, Jose M. Martín-Alvarez, Jesús M. Martínez-Ilarduya
Publikováno v:
UVaDOC. Repositorio Documental de la Universidad de Valladolid
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Producción Científica
A polymer [Pd(CH2SO2C6H4Me)2]n is obtained by thermolysis of cis-[Pd(CH2SO2C6H4Me)2(NCMe)2] to release the MeCN ligands. The corresponding coordination sites are then occupied by weak Pd–O bonds, easier to break than th
A polymer [Pd(CH2SO2C6H4Me)2]n is obtained by thermolysis of cis-[Pd(CH2SO2C6H4Me)2(NCMe)2] to release the MeCN ligands. The corresponding coordination sites are then occupied by weak Pd–O bonds, easier to break than th
Autor:
Celeste, Pérez-Briso, Ana M, Gallego, Jose M, Martín-Alvarez, Jesús M, Martínez-Ilarduya, Pablo, Espinet
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 46(25)
A polymer [Pd(CH
Publikováno v:
Organometallics. 30:611-617
The kinetics of the Stille reaction between C6Cl2F3I and PhCCSnBu3 have been studied for the whole catalytic system and for transmetalations as separate steps. The use of (trifluorodichlorophenyl)palladium derivatives slows down the reactions and all
Autor:
Jose M. Martín-Alvarez, Raquel de la Cruz, Pablo Espinet, Jesús M. Martínez-Ilarduya, Ana M. Gallego
Publikováno v:
Journal of Organometallic Chemistry. 663:108-117
Detailed analysis of the 19F-NMR spectra of the boat-shaped complexes (NBu4)2[Pd2(μ-LL)2R4] (R=3,5-C6Cl2F3) (LL=pyrazolate (pz), 1; dimethylpyrazolate (dmpz), 2), HH- (head-to-head) and HT- (head-to-tail) (NBu4)2[Pd2(μ-LL)2R4] (LL=3-methylpyrazolat
Publikováno v:
Journal of the American Chemical Society. 122:11771-11782
The mechanism of the [PdL4]-catalyzed couplings between R−OTf (R = pentahalophenyl; L = PPh3, AsPh3) and Sn(CHCH2)Bu3 has been studied. The addition of LiCl favors the coupling for L = AsPh3 in THF but retards it for L = PPh3. Separate experiments
Publikováno v:
Inorganic chemistry. 39(5)
A reinvestigation of the NMR spectra of the complexes (NBu4)2[M2(mu-LL)2R4] (M = Pd, Ni, Pt, LL = pyrazolate (pz), 3,5-dimethylpyrazolate (dmpz), 3-methylpyrazolate (mpz), indazolate (indz), R = C6F5; M = Pd, LL = pz, dmpz, mpz, indz, R = 2,4,6-C6F3H