Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Ana Cristina Esqueda"'
Autor:
Ana Cristina Esqueda, M. Fernanda Ibarra-Vázquez, I. Idalia Rangel-Salas, José G. Alvarado-Rodríguez, Oracio Serrano
Publikováno v:
Journal of Molecular Structure. 1191:52-58
A new small family of Ru, Rh, and Ir piano-stool complexes partially containing the bulky acacdiMes, p-Cymene and Cp* ligands was synthetized and characterized. Their catalytic activity in transfer hydrogenation reaction was tested. The turn over fre
Autor:
Celia Maya, Eleuterio Álvarez, Jesús Campos, María F. Espada, Ana Cristina Esqueda, Joaquín López-Serrano, Ernesto Carmona, M.A. Rubio
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
idUS. Depósito de Investigación de la Universidad de Sevilla
instname
idUS. Depósito de Investigación de la Universidad de Sevilla
In this contribution we study experimentally and computationally some electrophilic cationic (η-CMeR)Rh complexes containing a cyclometalated bis(aryl) phosphine, PR′Ar. The phosphine Ar groups feature methyl substituents at the 2- and 6-positions
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a05286497cd5f8ec54e4bb13dea46eeb
http://hdl.handle.net/10261/169573
http://hdl.handle.net/10261/169573
Publikováno v:
Journal of Labelled Compounds and Radiopharmaceuticals. 55:29-38
A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation in a 3–4 g scale, utilizing D2 (0.5 bar) as the hydrogen isotope source and low catalyst loadings (0.01 mol%). The catalyst pre
Autor:
José E. V. Valpuesta, Salvador Conejero, Eleuterio Álvarez, Ana Cristina Esqueda, Ernesto Carmona Guzman
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
7 páginas, 3 figuras, 6 esquemas.
The synthesis of a series of rhodium and iridium complexes bearing bulky cyclopentadienyl or hydro(trispyrazolyl)borate ligands is described. The rhodium cyclopentadienyl and hydrotris(pyrazolyl)borate diene co
The synthesis of a series of rhodium and iridium complexes bearing bulky cyclopentadienyl or hydro(trispyrazolyl)borate ligands is described. The rhodium cyclopentadienyl and hydrotris(pyrazolyl)borate diene co
Autor:
A. Dean Sherry, Luis M. De León-Rodríguez, S. James Ratnakar, José C. Alvarado-Monzón, Jorge A. López, Gabriel Andreu-de-Riquer, Ana Cristina Esqueda, Angelo J. M. Lubag
Publikováno v:
Journal of the American Chemical Society. 131:11387-11391
The properties of a novel Gd(3+)-based MRI zinc sensor are reported. Unlike previously reported Gd(3+)-based MRI contrast agents, this agent (GdL) differs in that the agent alone binds only weakly with human serum albumin (HSA), while the 1:2 GdL:Zn(
Publikováno v:
Tetrahedron Letters. 47:6937-6940
A high yielding N-trans diprotection procedure for cyclen has been developed by using succinimide carbamate derivates of Boc and Cbz and chloroformate protecting groups.
Autor:
Abel de Cózar, Ernesto Carmona, Ana Cristina Esqueda, Luis Sánchez, Jesús Campos, Celia Maya, Eleuterio Álvarez, Joaquín López-Serrano, Fernando P. Cossío
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
3 páginas, 2 figuras, 1 tabla, 3 esquemas.
The synthesis and structural characterization of a mixed-sandwich (η5-C5Me5)Rh(III) complex of the cyclometalated phosphine PMeXyl2 (Xyl = 2,6-C6H3Me2) with unusual κ4-P,C,C′,C′′ coordination (
The synthesis and structural characterization of a mixed-sandwich (η5-C5Me5)Rh(III) complex of the cyclometalated phosphine PMeXyl2 (Xyl = 2,6-C6H3Me2) with unusual κ4-P,C,C′,C′′ coordination (
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
3 páginas, 1 figura, esquemas.
The Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2
The Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2
Autor:
Ernesto Carmona, José E. V. Valpuesta, Ana Cristina Esqueda, Eleuterio Álvarez, Salvador Conejero, Celia Maya
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
idUS. Depósito de Investigación de la Universidad de Sevilla
instname
idUS. Depósito de Investigación de la Universidad de Sevilla
23 páginas, 5 figuras, 6 esquemas.
Complexes TptolRh(C2H4)2 (1a) and TptolRh(CH2C(Me)C(Me)CH2) (1b) have been prepared by reaction of KTptol with the appropriate [RhCl(olefin)2]2 dimer (Tptol means hydrotris(3-p-tolylpyrazol-1-yl)borate). The t
Complexes TptolRh(C2H4)2 (1a) and TptolRh(CH2C(Me)C(Me)CH2) (1b) have been prepared by reaction of KTptol with the appropriate [RhCl(olefin)2]2 dimer (Tptol means hydrotris(3-p-tolylpyrazol-1-yl)borate). The t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::57e6356830060b6fbc9da88707828bfb
http://hdl.handle.net/10261/37924
http://hdl.handle.net/10261/37924
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
9 páginas, 7 figuras, 6 esquemas.
Rh(I) complexes of the type (η5-C5Me4R)Rh(olefin)2 have been successfully synthesized through a novel procedure that makes use of zincocenes, Zn(C5Me4R)2, as mild cyclopentadienyl transfer reagents. This metho
Rh(I) complexes of the type (η5-C5Me4R)Rh(olefin)2 have been successfully synthesized through a novel procedure that makes use of zincocenes, Zn(C5Me4R)2, as mild cyclopentadienyl transfer reagents. This metho
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d528773b555a06057b3980fda32092ec
http://hdl.handle.net/10261/37695
http://hdl.handle.net/10261/37695