Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2

Autor: Kristoffer Kortsen, Magnus W. D. Hanson-Heine, Franck D'Agosto, Arnaldo F. da Silva Filho, Steven M. Howdle, Vincenzo Taresco, Jonathan D. Hirst, Ana A. C. Pacheco, Muriel Lansalot

Publikováno v: Chemical Science
Chemical Science, The Royal Society of Chemistry, 2021, 12, pp.1016-1030. ⟨10.1039/d0sc05281g⟩
Pacheco, A A C, Filho, A F D S, Kortsen, K, Hanson-Heine, M W D, Taresco, V, Hirst, J D, Lansalot, M, D'Agosto, F & Howdle, S M 2020, ' Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2 ', Chemical Science . https://doi.org/10.1039/D0SC05281G

Reversible addition–fragmentation chain transfer (RAFT) dispersion polymerisation of methyl methacrylate (MMA) is performed in supercritical carbon dioxide (scCO2) with 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT) present as chai

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ae63ac40013c9a9c9b5d837a51c87ddd
https://doi.org/10.1039/d0sc05281g

A ‘greener’ one-pot synthesis of monoterpene-functionalised lactide oligomers

Autor: Dara M. O'Brien, Ana A. C. Pacheco, Ryan R. Larder, Robert Cavanagh, Eduards Krumins, Alice J. Haddleton, Steven M. Howdle, Vincenzo Taresco, Cameron Alexander, Kristoffer Kortsen, Robert A. Stockman, Rachel L. Atkinson

© 2020 Elsevier Ltd In this work we aimed to achieve a totally sustainable Ring Opening Polymerisation (ROP) process, by harmonising the use of naturally occurring or derivable initiators and the green solvent 2-Methyltetrahydrofuran (2-MeTHF). Firs

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2734bb7b6962a850d93c36139f7b3823