Synthesis and Characterization of Heterometallic Rings Templated through Alkylammonium or Imidazolium Cations

Autor: Rajeh Alotaibi, Amy Booth, Edmund Little, Adam Brookfield, Amritroop Achari, Selena J. Lockyer, Grigore A. Timco, George F. S. Whitehead, Iñigo J. Vitórica-Yrezábal, Nicholas F. Chilton, Rahul R. Nair, David Collison, Richard E. P. Winpenny

Publikováno v: Alotaibi, R, Booth, A, Little, E, Brookfield, A, Achari, A, Lockyer, S J, Timco, G A, Whitehead, G F S, Vitorica-Yrezabal, I, Chilton, N F, Nair, R R, Collison, D & Winpenny, R E P 2023, ' Synthesis and Characterization of Heterometallic Rings Templated through Alkylammonium or Imidazolium Cations ', Dalton Transactions . https://doi.org/10.1039/D3DT00982C

We report the synthesis and structural characterization of a series of heterometallic rings templated via alkylammonium or imidazolium cations. The template and preference of each metal’s coordination geometry can control the structure of heteromet

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::024357cf126509ff0998976c4d25b9db
https://research.manchester.ac.uk/en/publications/f88cfa6a-fe93-4f30-82cd-10abe30220e9

Alternating Superconducting and Charge Density Wave Monolayers within Bulk 6R-TaS2

Autor: Amritroop Achari, Jonas Bekaert, Vishnu Sreepal, Andrey Orekhov, Piranavan Kumaravadivel, Minsoo Kim, Nicolas Gauquelin, Premlal Balakrishna Pillai, Johan Verbeeck, Francois M. Peeters, Andre K. Geim, Milorad V. Milošević, Rahul R. Nair

Publikováno v: Achari, A, Bekaert, J, Sreepal, V, Orekhov, A, Kumaravadivel, P, Kim, M, Gauquelin, N, Balakrishna Pillai, P, Verbeeck, J, Peeters, F M, Geim, A K, Milošević, M V & Nair, R R 2022, ' Alternating Superconducting and Charge Density Wave Monolayers within Bulk 6R-TaS2 ', Nano Letters . https://doi.org/10.1021/acs.nanolett.2c01851
Nano Letters

Van der Waals (vdW) heterostructures continue to attract intense interest as a route of designing materials with novel properties that cannot be found in naturally occurring materials. Unfortunately, this approach is currently limited to only a few l

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eb6d0691988202844091a19112657d12
https://pubs.acs.org/doi/10.1021/acs.nanolett.2c01851

Light induced in situ post-modification of clay-chromophore hybrids for multiple white light emissions

Autor: Ankit Jain, Muthuswamy Eswaramoorthy, Subi J. George, Amritroop Achari

Publikováno v: Journal of Materials Chemistry C. 4:2748-2751

In this study, soft clay chromophore hybrids were used to demonstrate a photo-modification strategy, in which a white light standard can be converted into a different white light standard via in situ generation of a blue emitting chromophore. This st

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0459a3c99e17fd3065f260de050f46a7
https://doi.org/10.1039/c5tc03319e

MOF–aminoclay composites for superior CO2 capture, separation and enhanced catalytic activity in chemical fixation of CO2

Autor: Muthusamy Eswaramoorthy, Anindita Chakraborty, Amritroop Achari, Tapas Kumar Maji

Publikováno v: Chemical Communications. 52:11378-11381

We delineate the growth and stabilization of ultra-small (2–3 nm) {Cu3(BTC)2(H2O)2·xH2O} MOF nanoparticles on a 2D layered aminoclay template. The composite shows significant CO2 uptake (5.35 mmol g−1 at 298 K, 1 bar; 46% higher than pristine bu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e0cb26ee3dd98a2e3dfa2ac4b0caed9a
https://doi.org/10.1039/c6cc05289d

Shining light on clay–chromophore hybrids: layered templates for accelerated ring closure photo-oxidation

Autor: Ankit Jain, Nivin Mothi, Subi J. George, Muthuswamy Eswaramoorthy, Amritroop Achari

Publikováno v: Chemical Science. 6:6334-6340

Templates with specific microenvironments have been long employed to facilitate specialized reactions. From enzymes to metal organic frameworks (MOFs), various systems have exerted their prowess to affect specific chemical reactions. Here we report,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0869e9f223ad1ab627d4508809fe5053
https://doi.org/10.1039/c5sc02215k