Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Amit Simlandy"'
The catalytic enantioselective synthesis of α-chiral alkenes and alkynes represents a powerful strategy for rapid generation of molecular complexity. Herein, we report a transient directing group facilitated site-selective palladium-catalyzed reduct
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::619234ffcbcd9586e8f4380b8198860b
https://doi.org/10.26434/chemrxiv-2022-h8w0k
https://doi.org/10.26434/chemrxiv-2022-h8w0k
We report a redox-neutral catalytic coupling of nitroalkanes and unactivated alkenes that proceeds by a directed carbopalladation mechanism. The reaction is uniquely enabled by the combination of PdI2 as the precatalyst and HFIP solvent. Structurally
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44f6c386f2614578f10beb890a8b4ea6
https://doi.org/10.26434/chemrxiv-2022-1q5dw-v2
https://doi.org/10.26434/chemrxiv-2022-1q5dw-v2