Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Ami Y. Patel"'
Publikováno v:
Journal of Catalysis. 364:415-425
Group 4 (Ti and Zr) and 5 (Nb and Ta) atoms substituted into the *BEA zeolite framework (M-BEA) irreversibly activate hydrogen peroxide (H2O2) and form pools of metal-hydroperoxide (M-OOH) and peroxide (M-(η2-O2)) intermediates active for the oxidat
Autor:
E. Zeynep Ayla, Michael J. Cordon, Alayna M. Johnson, Jeffrey Greeley, Rajamani Gounder, David W. Flaherty, Brandon C. Bukowski, Daniel T. Bregante, Ami Y. Patel
Publikováno v:
Journal of the American Chemical Society. 141(18)
Hydrophobic voids within titanium silicates have long been considered necessary to achieve high rates and selectivities for alkene epoxidations with H2O2. The catalytic consequences of silanol groups and their stabilization of hydrogen-bonded network