Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Amani Alhifthi"'
Autor:
Jinling Li, Mahima Sharma, Richard Meek, Amani Alhifthi, Zachary Armstrong, Niccolay Madiedo Soler, Ethan D. Goddard-Borger, James N. Blaza, Gideon J. Davies, Spencer J. Williams
Sulfolactate (SL) is a short-chain organosulfonate that is an important reservoir of sulfur in the biosphere. SL is produced by oxidation of sulfolactaldehyde (SLA), which in turns derives from sulfoglycolysis of the sulfosugar sulfoquinovose, or thr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c43d6837048411697bd909da64fa1e51
https://doi.org/10.1101/2023.03.13.532361
https://doi.org/10.1101/2023.03.13.532361
Autor:
Amani Alhifthi, Spencer J. Williams
Publikováno v:
The Journal of organic chemistry. 86(14)
1,2-trans-Glycosides hydrolyze through different mechanisms at different pH values, but systematic studies are lacking. Here, we report the pH-rate constant profile for the hydrolysis of 4-nitrophenyl β-D-glucoside. An inverse kinetic isotope effect
Autor:
Amani Alhifthi, Spencer Williams
1,2-trans-Glycosides hydrolyze through different mechanisms at different pH values, but systematic studies are lacking. Here we report the pH-rate constant profile for the hydrolysis of 4-nitrophenyl β-D-glucoside. An inverse kinetic isotope effect
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1f76de773d6eb53d47be977122277729
https://doi.org/10.26434/chemrxiv.13735084.v7
https://doi.org/10.26434/chemrxiv.13735084.v7
Autor:
Amani Alhifthi, Spencer Williams
1,2-trans-Glycosides hydrolyze through different mechanisms at different pH values, but systematic studies are lacking. Here we report the pH-rate constant profile for the hydrolysis of 4-nitrophenyl β-D-glucoside. An inverse kinetic isotope effect
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d28fe9b10c38555477c1e0dea37e602a
https://doi.org/10.26434/chemrxiv.13735084.v4
https://doi.org/10.26434/chemrxiv.13735084.v4
Publikováno v:
Organicbiomolecular chemistry. 15(47)
A structural, spectroscopic and computational study of a series of oximes was undertaken to investigate how geometric and structural changes relevant to the reaction coordinate for the Beckmann reaction (normal Beckmann) and Beckmann fragmentation (a