A New {Dy5} Single-Molecule Magnet Bearing the Schiff Base Ligand N-Naphthalidene-2-amino-5-chlorophenol

Autor: Dimitris I. Alexandropoulos, Alysha A. Alaimo, Di Sun, Theocharis C. Stamatatos

Publikováno v: Magnetochemistry, Vol 4, Iss 4, p 48 (2018)

A new {Dy5} cluster compound has been synthesized and structurally characterized from the initial use of the Schiff base ligand N-naphthalidene-2-amino-5-chlorophenol (nacpH2) in coordination chemistry. The 1:1 reaction between Dy(hpd)3∙2H2O and na

Externí odkaz: https://doaj.org/article/65ab6e44272740b4a3d0ff2956e20fc7

Structural Diversities in Heterometallic Mn–Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High- and Low-Valent States of the Oxygen-Evolving Complex

Autor: Sayak Das Gupta, Evangelia S. Koumousi, Alysha A. Alaimo, Vassilis Psycharis, Chaoran Li, Laura J. McCormick, Luís Cunha-Silva, Theocharis C. Stamatatos, Simon J. Teat, Shreya Mukherjee, Catherine P. Raptopoulou, George Christou, Albert Escuer

Publikováno v: Alaimo, AA; Koumousi, ES; Cunha-Silva, L; McCormick, LJ; Teat, SJ; Psycharis, V; et al.(2017). Structural Diversities in Heterometallic Mn-Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High-and Low-Valent States of the Oxygen-Evolving Complex. Inorganic Chemistry, 56(17), 10760-10774. doi: 10.1021/acs.inorgchem.7b01740. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/8fw5p18f

© 2017 American Chemical Society. One-pot reactions between the [Mn3O(O2CPh)6(py)x]+/0triangular precursors and either CaBr2·xH2O or CaCl2·6H2O, in the presence of salicylhydroxamic acid (shaH2), have afforded the heterometallic complexes [MnIII4C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4b421bd0c7fc1615faf455e7ea636828
https://doi.org/10.1021/acs.inorgchem.7b01740

Structural and Magnetic Variations in a Family of Isoskeletal, Oximate-Bridged {Mn

Autor: Alysha A, Alaimo, Anne, Worrell, Sayak Das, Gupta, Khalil A, Abboud, Christos, Lampropoulos, George, Christou, Theocharis C, Stamatatos

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 24(11)

The self-assembly reaction of MnCl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::d415c2d3b2ad38fc6010c389549d489f
https://pubmed.ncbi.nlm.nih.gov/29315881

Emissive {Mn4(III)Ca} clusters with square pyramidal topologies: syntheses and structural, spectroscopic, and physicochemical characterization

Autor: Alysha A. Alaimo, Luís Cunha-Silva, Daisuke Takahashi, Theocharis C. Stamatatos, George Christou

Publikováno v: Inorganic chemistry. 54(5)

The one-pot reactions between Mn(ClO4)2·6H2O, Ca(ClO4)2·4H2O, and the potentially tetradentate (N,O,O,O) chelating/bridging ligand salicylhydroxime (shiH3), resulting from the in situ metal ion-assisted amide-iminol tautomerism of salicylhydroxamic

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3498a84ad755e43dce2712733bf74e36
https://pubmed.ncbi.nlm.nih.gov/25478943