Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Aluminyls"'
Publikováno v:
Inorganic chemistry. 61(51)
In this work, the mechanism of the insertion reaction of 3-hexyne into Cu-Al and Au-Al bonds in M-aluminyl (M = Cu, Au) complexes is computationally elucidated. The mechanism is found to be radical-like, with the Cu-Al and Au-Al bonds acting as nucle
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::40ec79f4e9e60c4bce0f2b38170f1afb
https://pubmed.ncbi.nlm.nih.gov/36493466
https://pubmed.ncbi.nlm.nih.gov/36493466
Publikováno v:
Inorganic Chemistry
Anionic aluminum(I) anions (“aluminyls”) are the most recent discovery along Group 13 anions, and the understanding of the unconventional reactivity they are able to induce at a coordinated metal site is at an early stage. A striking example is t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9840c571bd81abd90a85b580c700cc43
https://doi.org/10.1021/acs.inorgchem.1c03579
https://doi.org/10.1021/acs.inorgchem.1c03579