Zobrazeno 1 - 10
of 38
pro vyhledávání: '"Aluminium amalgam"'
Autor:
Leszek Konopski, Karol Grela
Publikováno v:
Tetrahedron. 66:3608-3613
Substituted five-membered cyclic nitrones (pyrroline N-oxides) have been obtained in good to high yields from tertiary γ-nitro ketones and nitriles employing aluminium amalgam as a reducing agent in moist diethyl ether or THF. Attempts to obtain cyc
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 628:421-427
Sulfur-substituted methylmercury compounds [Hg(CH2SR)2](1a, R = Me; 1b, R = Ph) react with aluminium amalgam in refluxing toluene with transmetallation to give homoleptic tris(thiomethyl)aluminium complexes [Al(CH2SR)3](2a, R = Me; 2b, R = Ph) (degre
Publikováno v:
Tetrahedron Letters. 41:6665-6668
The titled triazine can be alkylated with LDA and a variety of alkyl halides: subsequent reduction with aluminium amalgam cleaves the naphthotriazine moiety to afford substituted α amino acids in excellent overall yields; the sequence defines a nove
Autor:
Makbule Burkut Koçak, Özer Bekaroĝlu
Publikováno v:
Journal of Coordination Chemistry. 47:359-368
A new soluble vic-dioxime, l,4-bis(2-methoxyethyl-2, 3-bis(hydroxyimino)-5, 6-diphenylpiper-azine (LH2) has been synthesized as a mixture of isomers from dicyan di-N-oxide and 1, 2-diphe-nyl-l,2-bis(2′-methoxyethylamino)ethane, 1, which has been pr
Publikováno v:
Tetrahedron Letters. 36:7925-7928
Di-α-alkylated-α-(β-keto sulfone) alkynes provide a facile entry to trisubstituted allenes upon treatment with aluminium amalgam.
Publikováno v:
Liebigs Annalen. 1995:523-535
Oxidation of dioxime 2a with NBS gave 3 and 4. A chair-boat conformation has been established for 3 by X-ray diffraction analysis, while 4 seems to exist in a chair-chair conformation on the basis of NMR data. m-Chloroperbenzoic acid oxidation of dio
Autor:
T. R. Ramachandran
Publikováno v:
Transactions of the Indian Ceramic Society. 54:117-123
A brief presentation is made of the raw materials for alumina ceramics. The important source is the alumina trihydrate resulting from the Bayer process. Purification of the Bayer aluminate liquor to minimise organics, iron oxide and silica, reduction
Autor:
Andrew J. Robinson, Peter B. Wyatt
Publikováno v:
Tetrahedron. 49:11329-11340
The Reformatsky reagent tert-butoxycarbonylmethylzinc bromide adds in high yields to N-sulfonylimines, e.g. 1a–1d, derived by condensation of benzaldehyde dimethyl acetal with methanesulfonamide, toluene-4-sulfonamide, 4-(methoxycarbonyl)benzenesul
Publikováno v:
Tetrahedron Letters. 34:353-356
The sonochemical reductive opening of α, β-epoxy ketones and their α′-oxygenated (-OH or -OAc) analogs by aluminium amalgam allows shorter reaction times, better yields of the respective β-hydroxy ketones and minimization of by-products. The ra
Autor:
Andrew J. Robinson, Peter B. Wyatt
Publikováno v:
ChemInform. 25
The Reformatsky reagent tert-butoxycarbonylmethylzinc bromide adds in high yields to N-sulfonylimines, e.g. 1a–1d, derived by condensation of benzaldehyde dimethyl acetal with methanesulfonamide, toluene-4-sulfonamide, 4-(methoxycarbonyl)benzenesul