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Autor:
David H. Burger, Nooshin Dibaji, Michael O. Agho, Allen R. Clague, Erach R. Talaty, Katherine M. Korst, Thomas L. Hendrixson, Tran T. Khanh, Roger A. Kell, Jana M. Behrens
Publikováno v:
Synthetic Communications. 11:455-461
The reaction of aziridinones (1a-1d) with tert-butyllithium at room temperature affords α-hydroxy imines (5ax-5dx).1 One possible pathway leading to these products involves the formation of 2 as an intermediate, followed by rearrangement to 3. In fa