Zobrazeno 1 - 10
of 90
pro vyhledávání: '"Alison M. Stuart"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 20, Iss 1, Pp 1785-1793 (2024)
The ability to investigate hypervalent iodine(V) fluorides has been limited primarily by their difficult preparation traditionally using harsh fluorinating reagents such as trifluoromethyl hypofluorite and bromine trifluoride. Here, we report a mild
Externí odkaz:
https://doaj.org/article/c40c32d53c5c482ca6089a19a9c08295
Publikováno v:
Organic & Biomolecular Chemistry. 18:6140-6146
Activated aromatics were reacted with two different fluoroidoane reagents 1 and 2 in the presence of triflic acid to prepare only the para-substituted diaryliodonium salts. With fluoroiodane 1 the unsymmetrical diaryliodonium salts contained an ortho
A new and efficient strategy for the rapid formation of novel fluorinated tetrahydropyridazines and dihydrooxazines has been developed by fluorocyclisation of β,γ-unsaturated hydrazones and oximes with the fluoroiodane reagent. Mechanochemical synt
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e383884f6282fe4e75f49399918027e5
https://orca.cardiff.ac.uk/id/eprint/145310/1/d1cc02587b.pdf
https://orca.cardiff.ac.uk/id/eprint/145310/1/d1cc02587b.pdf
Publikováno v:
Organic & Biomolecular Chemistry. 16:7170-7173
Hexafluoroisopropan-2-ol (HFIP) is an excellent solvent for promoting fluorinations with the hypervalent fluoroiodane reagent 1 and crucially, it removes the need for transition metals or TREAT-HF activators. The fluoroiodane reagent 1 was used in HF
Publikováno v:
RSC Advances. 5:16501-16506
The isolation of iodonium ylide 8, from the reaction of fluoroiodane 1 with ethyl 3-oxo-3-phenylpropanoate 5 in the presence of potassium fluoride, provides strong evidence that 1,3-dicarbonyl compounds undergo an addition reaction with fluoroiodane
Publikováno v:
ChemInform. 47
Publikováno v:
Journal of Fluorine Chemistry. 131:1133-1143
A series of dibenzo-18-crown-6 lariat ethers containing two C7H15 (11), (CH2)2C6F13 (14), (CH2)2C8F17 (15), NHC7H15 (18) and NHCH2C6F13 (19) sidearms were prepared and the single crystal X-ray structure of cis-4,4′-di(1H,1H,2H,2H-perfluorodecyl)-di
Publikováno v:
Advanced Synthesis & Catalysis. 352:2241-2250
New perfluoroalkylated polystyrene resins have been prepared by the suspension polymerisation of 4-(perfluoro-n-octyl)styrene. The evaluation of these highly fluorinated insoluble materials as catalyst supports for rhodium-catalysed hydrogenation of
Publikováno v:
Journal of Fluorine Chemistry. 130:942-950
Palladium(II), platinum(II), rhodium(I), rhodium(III) and iridium(III) complexes of the tridecafluorohexyl-derivatised diphenylethylphosphinite (PPh 2 OC 2 H 4 R f ), phenyldiethylphosphonite {PPh(OC 2 H 4 R f ) 2 }, triethylphosphite {P(OC 2 H 4 R f
Publikováno v:
Journal of Fluorine Chemistry. 130:615-620
Phosphonic acids [(HO) 2 P(O)C 2 H 4 C n F 2 n +1 ] ( n = 4, 6) and [(HO) 2 P(O)C 6 H 4 -4-C n F 2 n +1 ] ( n = 0, 1, 6) have been prepared in good yields. Deprotonation and reaction with cis -[PtCl 2 (PPh 3 ) 2 ] affords fluorinated platinum complex