Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Alireza Karbakhsh, Ravari"'
Publikováno v:
Inorganic Chemistry. 59:13880-13887
Ru-based coordination compounds have important applications as photosensitizers and catalysts. [RuII(bpy)2(bpyNO)]2+ (bpy = 2,2′-bipyridine and bpyNO = 2,2′-bipyridine-N-oxide) was reported to be e...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3e935cbe6d163245d2e669af4612bc73
https://doi.org/10.1021/acs.inorgchem.0c01446
https://doi.org/10.1021/acs.inorgchem.0c01446
Publikováno v:
Angewandte Chemie International Edition. 59:13502-13505
Hypervalent FeV =O species are implicated in a multitude of oxidative reactions of organic substrates, as well as in catalytic water oxidation, a reaction crucial for artificial photosynthesis. Spectroscopically characterized FeV species are exceedin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d2a708ffc093df1a799fb678c116a5bd
https://doi.org/10.1002/anie.202003278
https://doi.org/10.1002/anie.202003278
Publikováno v:
ACS Catalysis. 10:5299-5308
The realization of artificial photosynthesis requires the design of fast and durable water oxidation catalysts that can be incorporated into future sunlight-to-chemical-fuels assemblies. Here we re...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a01ac758416db8a3a44aefb37cd5f984
https://doi.org/10.1021/acscatal.0c00488
https://doi.org/10.1021/acscatal.0c00488
Unraveling the Mechanism of Catalytic Water Oxidation via de Novo Synthesis of Reactive Intermediate
Autor:
Yulia Pushkar, Alireza Karbakhsh Ravari, Lifen Yan, Whitney Weinschenk, Allison Page, Yuliana Pineda-Galvan, Guibo Zhu, Roman Ezhov
Publikováno v:
Journal of the American Chemical Society. 142:884-893
Artificial photosynthesis could promise abundant, carbon-neutral energy, but implementation is currently limited by a lack of control over the multi-electron catalysis of water oxidation. Discoveries of the most active catalysts still rely heavily on
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cd4993508ffa5952c278703aa9939fe8
https://doi.org/10.1021/jacs.9b10265
https://doi.org/10.1021/jacs.9b10265
Publikováno v:
The Journal of Physical Chemistry Letters. 10:5284-5291
The biological generation of oxygen by the oxygen-evolving complex (OEC) in photosystem II (PS II) is one of nature's most important reactions. The OEC is a Mn4Ca cluster that has multiple Mn-O-Mn and Mn-O-Ca bridges and binds four water molecules. P
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::10ba9abfb92003fe6c520756b2a7dce9
https://doi.org/10.1021/acs.jpclett.9b01255
https://doi.org/10.1021/acs.jpclett.9b01255
Autor:
Yulia Pushkar, Liubov M. Lifshits, Alireza Karbakhsh Ravari, Sergei Shmakov, Randolph P. Thummel, Yuliana Pineda-Galvan, Nattawut Kaveevivitchai
Publikováno v:
Journal of Catalysis. 375:1-7
Artificial photosynthesis could promise cheap and abundant energy but requires the discovery of new water oxidation catalysts. A RuV = O 7-coordinate intermediate is implicated in the reactivity of the fastest water oxidation catalysts. Previously we
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::043295f2af80d1408126caed27ab7139
https://doi.org/10.1016/j.jcat.2019.05.014
https://doi.org/10.1016/j.jcat.2019.05.014
Publikováno v:
Chem Catal
Catalytic water oxidation is a required process for clean energy production based on the concept of artificial photosynthesis. Here, we provide in situ spectroscopic and computational analysis for the closest known photosystem II analog, [Co(4)O(4)](
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afc77ecd3d0bab30bd007e9768b8bf17
https://europepmc.org/articles/PMC10296785/
https://europepmc.org/articles/PMC10296785/
Development of economically viable artificial photosynthesis requires use of 3d metal-based catalysts. Water oxidation by [Co4O4]n+ cubane mimics water splitting by CaMn4O5 cluster in Nature but the exact mechanism of O-O bond formation is presently
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a1fa3e71782d7b039f0be1fafe20982d
https://doi.org/10.21203/rs.3.rs-93543/v1
https://doi.org/10.21203/rs.3.rs-93543/v1
Autor:
Alireza, Karbakhsh Ravari, Yuliana, Pineda-Galvan, Alexander, Huynh, Roman, Ezhov, Yulia, Pushkar
Publikováno v:
Inorganic chemistry. 59(19)
Ru-based coordination compounds have important applications as photosensitizers and catalysts. [Ru
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::defbc6ab475bf83ed7a1aecd629913b1
https://pubmed.ncbi.nlm.nih.gov/32924462
https://pubmed.ncbi.nlm.nih.gov/32924462
Publikováno v:
Angewandte Chemie (International ed. in English). 59(32)
Hypervalent Fe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::0f2195d236318ef8898d776a78e28eab
https://pubmed.ncbi.nlm.nih.gov/32369663
https://pubmed.ncbi.nlm.nih.gov/32369663