Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Alice K. Hui"'
Publikováno v:
Inorganic Chemistry. 53:3039-3047
Binding an electron deficient pincer ligand which strongly dictates planar, mer stereochemistry, to a metal which prefers tetrahedral structure, e.g., d(10) CuCl, is explored for possible intramolecular redox chemistry. Experiment shows that the pinc
Autor:
Alice K. Hui, Kenneth G. Caulton, René W. Buell, Nobuyuki Komine, Chun-Hsing Chen, Maren Pink
Publikováno v:
Inorganic Chemistry. 53:1361-1369
A new pincer ligand is synthesized to be dianionic, with the potential to be redox active. It has pyrrrole rings attached to both ortho sites of a pyridine, as the linking element. This H2L can be doubly deprotonated and then used to replace two chlo
Publikováno v:
Dalton Trans.. 43:7958-7963
The synthesis and characterization of a "super-saturated" six-coordinate complex of monovalent copper (PF6(-) salt) and the potentially oxidizing pincer ligand 2,6, bis-(methyl tetrazinyl)pyridine, btzp, are described. This cation has a structure wit
Autor:
Richard L. Lord, Kumar Parimal, Brian J. Cook, Alice K. Hui, Kenneth G. Caulton, Christopher R. Benson, Chun-Hsing Chen, Amar H. Flood
Publikováno v:
Dalton Trans.. 43:6513-6524
An unexpected doubling in redox storage emerging from a new pincer ligand upon bis-ligation of iron(ii) is described. When tetrazine arms are present at the two ortho positions of pyridine, the resulting bis-tetrazinyl pyridine (btzp) pincer ligand d
Publikováno v:
Inorganic chemistry. 53(7)
Two different neutral tridentate imine-donor pincer ligands interact with excess MCl2 (M = Co or Cu) to form compounds of the same stoichiometry, (LMCl2)2·MCl2, where the assembling force is the electron richness of the terminal chlorides on the LMC
Publikováno v:
Acta crystallographica. Section C, Structural chemistry. 70(Pt 3)
Reaction of a bis-tetrazinyl pyridine pincer ligand, btzp, with a vanadium(III) reagent gives not a simple adduct but dichlorido{3-methyl-6-[6-(6-methyl-1,2,4,5-tetrazin-3-yl-κN2)pyridin-2-yl-κN]-1,4-dihydro-1,2,4,5-tetrazin-1-yl-κN1}oxidovanadium