Sequential curing of off-stoichiometric thiol–epoxy thermosets with a custom-tailored structure

Autor: Xavier Ramis, Xavier Fernández-Francos, Alberto Belmonte, Silvia De la Flor, Angels Serra, Ali-Osman Konuray

Publikováno v: Recercat. Dipósit de la Recerca de Catalunya
instname
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)

A new dual-curing system based on sequential thiol-epoxy click polycondensation and epoxy anionic homopolymerization was studied. Formulations of diglycidyl ether of bisphenol A and trimethylolpropane tris(3-mercaptopropionate) with 1-methylimidazole

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b33c464c345a95a83e7ebd3d9f162f0a
https://doi.org/10.1039/c6py00099a

Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization

Autor: Xavier Ramis, Xavier Fernández-Francos, Angels Serra, Ali Osman Konuray

Publikováno v: European Polymer Journal
Recercat. Dipósit de la Recerca de Catalunya
instname
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)

Filiació URV: SI Dual curing systems find various uses in industry with the process flexibility they provide which allows tailoring properties at different curing stages in accordance with application requirements. A safe and efficient dual curing s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c08354a3083c3d8c64aa4665d41c1e5b
http://hdl.handle.net/20.500.11797/PC1914

Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization

Autor: Àngels Serra, Ali Osman Konuray, Xavier Fernández-Francos, Xavier Ramis

Publikováno v: European Polymer Journal
Repositori Institucional de la Universitat Rovira i Virgili
Universitat Rovira i virgili (URV)

Filiació URV: SI Dual curing systems find various uses in industry with the process flexibility they provide which allows tailoring properties at different curing stages in accordance with application requirements. A safe and efficient dual curing s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=RECOLECTA___::6066ff130a3e92b9df5777a8c8b559d9
http://hdl.handle.net/20.500.11797/PC1914

Latent curing of epoxy-thiol thermosets

Autor: Xavier Fernández-Francos, Ali Osman Konuray, Xavier Ramis

Publikováno v: Recercat. Dipósit de la Recerca de Catalunya
instname
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)

Epoxy-thiol curing is a click reaction which allows quantitative yield of the end products. The base-catalyzed reaction is rapid at low temperatures so it is most often desirable to harness reactivity by using latent catalysts. In this work, we used

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b73836ba6666e7b4eb5862b739ec3742
http://hdl.handle.net/2117/103949

Sequential curing of thiol-acetoacetate-acrylate thermosets by latent Michael addition reactions

Autor: Xavier Fernández-Francos, Freddy Liendo, Marco Sangermano, Angels Serra, Ali Osman Konuray, Xavier Ramis

Publikováno v: Recercat. Dipósit de la Recerca de Catalunya
instname
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)

Thiol-acetoacetate-acrylate ternary dual-curing thermosets were prepared by a sequential process consisting of thiol-Michael addition to acrylates at room temperature followed by Michael addition of acetoacetates to acrylates at moderately elevated t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::81376e402c7b988868465c66d00bfcd6
http://hdl.handle.net/2117/103098