Zobrazeno 1 - 2
of 2
pro vyhledávání: '"Aliénor Jeandin"'
Autor:
Antoine Bruneau-Voisine, Aliénor Jeandin, Serena Fantasia, Etienne Stihle, Florian Bourriquen
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(38)
An efficient and cost-effective two-step synthesis of diaminopyridines, fundamental building blocks of biologically active compounds, is reported. The advantages over previously reported routes include cost and wider availability of the bromo-chlorop
Publikováno v:
Journal of the American Chemical Society. 144(37):16737-16743
Herein, we report the first catalytic one-step synthesis of cyclopropenium cations (CPCs) with readily available alkynes and hypervalent iodine reagents as carbyne sources. Key to the process is the catalytic generation of a novel Rh-carbynoid that f