Zobrazeno 1 - 10 of 179 pro vyhledávání: '"Alfred P, Sattelberger"'
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Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum(iv) chloride and tungsten(iv) chloride
Autor: Thomas E. Shaw, Timothy J. Diethrich, Charlotte L. Stern, Brian L. Scott, Titel Jurca, Thomas M. Gilbert, Alfred P. Sattelberger
Publikováno v: Dalton Transactions. 51:7856-7863
The bis(diethyl ether) and 1,2-dimethoxyethane (dme) adducts of molybdenum(IV) chloride and tungsten(IV) chloride are valuable starting materials for a variety of synthetic inorganic and organometallic reactions. Despite the broad utility and extensi
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c645291c2a0a023281ae5821d80ceb69
https://doi.org/10.1039/d2dt00787h
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3
Study of the Electronic Structure of M2(CH2CMe3)6 (M = Mo, W) by Photoelectron Spectroscopy and Density Functional Theory
Autor: Monica de Simone, Marcello Coreno, Roberta Totani, Nicolas E. Capra, Louis Messerle, Jennifer C. Green, Alfred P. Sattelberger
Publikováno v: Organometallics 41 (2021): 29–40. doi:10.1021/acs.organomet.1c00586
info:cnr-pdr/source/autori:de Simone, Monica; Coreno, Marcello; Totani, Roberta; Capra, Nicolas E.; Messerle, Louis; Green, Jennifer C.; Sattelberger, Alfred P./titolo:Study of the Electronic Structure of M-2(CH2CMe3)(6) (M = Mo, W) by Photoelectron Spectroscopy and Density Functional Theory/doi:10.1021%2Facs.organomet.1c00586/rivista:Organometallics/anno:2021/pagina_da:29/pagina_a:40/intervallo_pagine:29–40/volume:41
The valence electronic structures of two dinuclear alkyl compounds containing sigma(2)pi(4) triple bonds between group 6 metals, viz., M-2(CH2CMe3)(6) (M = Mo, W), have been investigated using a combination of molecular orbital theory and variable ph
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::683a18713340f082e22a1b9467bbc237
https://doi.org/10.1021/acs.organomet.1c00586
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4
'MoCl3(dme)' Revisited: Improved Synthesis, Characterization, and X-ray and Electronic Structures
Autor: Alfred P. Sattelberger, Titel Jurca, Brian L. Scott, Timothy J. Diethrich, Thomas E. Shaw, Thomas M. Gilbert
Publikováno v: Inorganic Chemistry. 60:12218-12225
"MoCl3(dme)" (dme = 1,2-dimethoxyethane) is an important precursor for midvalent molybdenum chemistry, particularly for triply Mo-Mo bonded compounds of the type Mo2X6 (X = bulky anionic ligand). However, its exact structural identity has been obscur
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7a991b351cbc4f971eb4bc0550429639
https://doi.org/10.1021/acs.inorgchem.1c01398
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5
Electrochemical Investigation of Low-Valent Multiply M≡M Bonded Group VI Dimers: A Standard Chemical Reduction Leads to an Unexpected Product
Autor: Massimiliano Delferro, Prajay Patel, Alon Chapovetsky, Alfred P. Sattelberger, Cong Liu, David M. Kaphan
Publikováno v: Organometallics. 39:4430-4436
The synthesis and investigation of multimetallic complexes bearing metal–metal bonds have been significantly advanced over the last 30 years with exciting applications across many fields. While the...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8df734fbfabe1ede65f21e49ca1822d8
https://doi.org/10.1021/acs.organomet.0c00533
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6
Crystal structure and Hirshfeld surface analysis of the elusive trichlorobis(diethyl ether)oxomolybdenum(V)
Autor: Titel Jurca, Alfred P. Sattelberger, Pierre LeMagueres, Thomas E. Shaw
Publikováno v: Acta Crystallographica Section C Structural Chemistry. 76:947-951
First reported in 1930, MoCl3O(Et2O)2 is a by-product of the reductive synthesis of MoCl4(OEt2)2 from MoCl5. We report herein the X-ray crystal structure and Hirshfeld surface characteristics of mer-MoCl3O(Et2O)2, or [MoCl3O(C4H10O)2]. The compound c
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::24b0fff1932ba390853e4bb97c4b5026
https://doi.org/10.1107/s2053229620011626
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9
Formation of Unsaturated Hydrocarbons and Hydrogen: Surface Chemistry of Methyltrioxorhenium(VII) in ALD of Mixed-Metal Oxide Structures Comprising Re(III) Units
Autor: Anil U. Mane, Devika Choudhury, Jeffrey W. Elam, David J. Mandia, Maximilian Gebhard, Angel Yanguas-Gil, Alfred P. Sattelberger, Steven Letourneau
Publikováno v: Chemistry of Materials. 31:7821-7832
We present the full investigation of the atomic layer deposition (ALD) of a mixed rhenium–aluminum oxide, namely ReAl2O3CH3, a material with tunable resistance, comprising the building unit of cond...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::291a69d229f2bb7da2826f8440323873
https://doi.org/10.1021/acs.chemmater.9b01408
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10
An Atomistic Understanding of the Unusual Thermal Behavior of the Molecular Oxide Tc2O7
Autor: Bradley C. Childs, Keith V. Lawler, Alfred P. Sattelberger, Daniel S. Mast, Paul M. Forster, Kenneth R. Czerwinski, Frederic Poineau
Publikováno v: Inorganic Chemistry. 58:5468-5475
The thermal behavior of Tc2O7 has been investigated by single-crystal X-ray diffraction of the solid state over a range of 80–280 K and by ab initio molecular dynamics (MD) simulations. The thermal expansion coefficient of the solid was experimenta
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3bc8e8e97d38f571bab289d3d088e9a0
https://doi.org/10.1021/acs.inorgchem.8b02368
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