Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Alfons M. Molenbroek"'
Publikováno v:
Topics in catalysis 52, 1303-1311 (2009). doi:10.1007/s11244-009-9314-1
The introduction of in situ techniques has had a vast impact on research and development in the area of heterogeneous catalysis as emphasized in many reviews and monographs. Recently, the number of in situ techniques that can give information at the
Publikováno v:
Synchrotron Radiation News. 22:12-16
Heterogeneous catalysts are complex and dynamic multicomponent systems, usually consisting of several elements and phases. The catalyst active sites are very sensitive to the environmental conditions (gas atmosphere, temperature, and pressure) and ma
Autor:
Andreas Stierle, Alfons M. Molenbroek
Publikováno v:
MRS Bulletin. 32:1001-1009
During the past few years, substantial effort has been devoted to developing new experimental techniques capable of delivering atomic-scale information on surfaces and nanoparticles under catalytic reaction conditions. Since the advent of surface sci
Autor:
Bjerne S. Clausen, Frank Berg Rasmussen, Jens Sehested, Herman T. Teunissen, Alfons M. Molenbroek
Publikováno v:
Applied Catalysis A: General. 267:165-173
Sintering is an important deactivation mechanism of nickel-based catalysts used for the production of synthesis gas and hydrogen in the steam reforming process. In this work sintering of nickel catalysts supported by aluminum oxide is studied by a co
Publikováno v:
Catalysis Letters. 92:29-34
The chemical state of arsenic deposited on a NiMoP/Al2O3 hydrotreating catalyst exposed to ppb levels of arsenic over several years in a refinery reactor has been studied by in situ EXAFS. In the as-received As-NiMoP catalyst, arsenic is exclusively
Publikováno v:
The Journal of Physical Chemistry B. 105:5450-5458
We discuss the design of a Ni−Au nanoparticle catalyst system, which is based on the detailed experimental and theoretical understanding of the alloying and the chemical reaction processes on single-crystal surfaces. The alloy formation and structu
Autor:
Lars P. Hansen, Christian Kisielowski, Henrik Topsøe, Michael Brorson, Alfons M. Molenbroek, Quentin M. Ramasse, Anna Carlsson, Stig Helveg
Publikováno v:
Angewandte Chemie International Edition. 49:2708-2710
Publikováno v:
The Journal of Physical Chemistry B. 102:10680-10689
In this paper we show a new application of the atomic layer epitaxy technique to prepare binary alloy nanoparticle catalysts on various supports. The technique is used to prepare Cu/Pd bimetallic catalysts on SiO2 and on γ-Al2O3. The samples were ch
Autor:
Poul L. Hansen, Gert Steffensen, David Nicholson, Arild Moen, Alfons M. Molenbroek, Bjerne S. Clausen
Publikováno v:
Chemistry of Materials. 9:1241-1247
In situ XAFS spectroscopic studies have been carried out at 450 °C on the hydrogen reduction of a rhenium-promoted Co3O4/Al2O3 catalyst. The results show that reduction at this temperature yields a...
Publikováno v:
The Journal of Physical Chemistry B. 101:1861-1868
We present extended X-ray absorption fine structure (EXAFS) and transmission electron microscopy (TEM) measurements on three zeolite-supported bimetallic Pt−Pd catalysts prepared by wet impregnation. Alloy formation and segregation of Pd to the sur