Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Alexis W. Mills"'
Autor:
Denis Leshchev, Andrew J. S. Valentine, Pyosang Kim, Alexis W. Mills, Subhangi Roy, Arnab Chakraborty, Elisa Biasin, Kristoffer Haldrup, Darren J. Hsu, Matthew S. Kirschner, Dolev Rimmerman, Matthieu Chollet, J. Michael Glownia, Tim B. van Driel, Felix N. Castellano, Xiaosong Li, Lin X. Chen
Publikováno v:
Leshchev, D, J. S. Valentine, A, Kim, P, Mills, A W, Roy, S, Chakraborty, A, Biasin, E, Haldrup, K, Hsu, D J, Kirschner, M S, Rimmerman, D, Chollet, M, Glownia, J M, van Driel, T B, Castellano, F N, Li, X & Chen, L X 2023, ' Revealing Excited-State Trajectories on Potential Energy Surfaces with Atomic Resolution in Real Time ', Angewandte Chemie-International Edition, vol. 62, e2023046 . https://doi.org/10.1002/anie.202304615
Photoexcited molecular trajectories on potential energy surfaces (PESs) prior to thermalization are intimately connected to the photochemical reaction outcome. The excited-state trajectories of a diplatinum complex featuring photo-activated metal–m
Autor:
Tae Wu Kim, Pyosang Kim, Alexis W. Mills, Arnab Chakraborty, Sarah Kromer, Andrew J. S. Valentine, Felix N. Castellano, Xiaosong Li, Lin X. Chen
Publikováno v:
The Journal of Physical Chemistry C. 126:11487-11497
Autor:
Pyosang Kim, Andrew J. S. Valentine, Subhangi Roy, Alexis W. Mills, Felix N. Castellano, Xiaosong Li, Lin X. Chen
Publikováno v:
Faraday Discussions. 237:259-273
Ultrafast excited state processes of transition metal complexes (TMCs) are governed by complicated interplays between electronic and nuclear dynamics, which demand a detailed understanding to achieve optimal functionalities of photoactive TMC-based m
Autor:
Subhangi Roy, Kevin Hoang, Xiaosong Li, Lin X. Chen, Andrew J. S. Valentine, Felix N. Castellano, Alexis W. Mills
Publikováno v:
The Journal of Physical Chemistry A. 125:9438-9449
A series of platinum(II) bimetallic complexes were studied to investigate the effects of ligands on both the geometric and electronic structure. Modulating the Pt-Pt distance through the bridging ligand architecture was found to dictate the nature of
Autor:
Arnab Chakraborty, Xiaosong Li, Andrew J. S. Valentine, Lin X. Chen, Felix N. Castellano, Subhangi Roy, Alexis W. Mills, Pyosang Kim
Publikováno v:
The Journal of Physical Chemistry Letters. 12:6794-6803
Intricate potential energy surfaces (PESs) of some transition metal complexes (TMCs) pose challenges in mapping out initial excited-state pathways that could influence photochemical outcomes. Ultrafast intersystem crossing (ISC) dynamics of four stru
Publikováno v:
Journal of chemical information and modeling. 62(13)
Reinforcement machine learning is implemented to survey a series of model potential energy surfaces and ultimately identify the global minima point. Through sophisticated reward function design, the introduction of an optimizing target, and incorpora
Autor:
Lin X. Chen, Andrew J. S. Valentine, Pyosang Kim, Felix N. Castellano, Xiaosong Li, Joseph J. Radler, Alexis W. Mills
Publikováno v:
The Journal of Chemical Physics. 152:169902
Autor:
Andrew J. S. Valentine, Felix N. Castellano, Joseph J. Radler, Alexis W. Mills, Xiaosong Li, Pyosang Kim, Lin X. Chen
Publikováno v:
The Journal of Chemical Physics. 151:114303
Bimetallic platinum complexes have interesting luminescent properties and feature long-lasting vibrational coherence and ultrafast intersystem crossing (ISC) after photoexcitation. Ultrafast triplet formation is driven by very strong spin-orbit coupl