Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Alexis Prieto"'
Publikováno v:
Advanced Synthesis & Catalysis. 364:4249-4254
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(43)
The first photo-mediated process enabling the generation of halide radicals by Halogen-Atom Transfer (XAT) is described. Contrary to radical transformations involving XAT reactivity, which exploit stable carbon radicals, this unique approach uses 1,2
Autor:
Emmanuel Magnier, Patrick Diter, Elsa Anselmi, Anne-Laure Barthelemy, Alexis Prieto, Martial Toffano, Jérôme Hannedouche
Publikováno v:
European Journal of Organic Chemistry. 2018:3764-3770
We report herein the preparation of ortho-vinylaryl S-trifluoromethylated sulfoximines through cross-coupling reactions. Two efficient palladium-catalyzed procedures (Stille and Suzuki) were developed, with use of ortho-iodo aryl sulfox-imines as sub
Publikováno v:
European Journal of Organic Chemistry. 2018:2378-2393
Publikováno v:
Angewandte Chemie (International Ed. in English)
Angewandte Chemie International Edition
Angewandte Chemie International Edition
We report herein that 4‐alkyl‐1,4‐dihydropyridines (alkyl‐DHPs) can directly reach an electronically excited state upon light absorption and trigger the generation of C(sp3)‐centered radicals without the need for an external photocatalyst.
Publikováno v:
Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩
Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2019, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩
Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩
Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2019, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩
International audience; We describe herein the photoredox-initiated 1,2-difunctionalization of alkene derivatives with N-chloro S-fluoroalkyl sulfoximines yielding novel fluoroalkyl sulfoximine scaffolds. The reaction is proposed to proceed through a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7b54b39dc565788c6a22a9bae69b5d17
https://hal.archives-ouvertes.fr/hal-02358288
https://hal.archives-ouvertes.fr/hal-02358288
Publikováno v:
Asian Journal of Organic Chemistry. 5:742-745
The copper-catalyzed azomethine trifluoromethylation of ketone-derived hydrazones with Togni′s hypervalent iodine(III)-CF3 reagent is described. The reaction gives rise to quaternary α-trifluoromethyl diazenes under mild conditions and is proposed
Publikováno v:
Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 55, pp.1885-1889. ⟨10.1002/ange.201510334⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2016, 55 (5), pp.1885-1889. ⟨10.1002/anie.201510334⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 55, pp.1885-1889. ⟨10.1002/ange.201510334⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2016, 55 (5), pp.1885-1889. ⟨10.1002/anie.201510334⟩
International audience; A palladium-catalyzed C(sp 2) À Hd ifluoromethylation of aldehyde-derived hydrazones using bromodifluorome-thylated compounds to affordt he corresponding functional-ized difluoromethylketone hydrazones has been established. I
Publikováno v:
Journal of Organic Chemistry
Journal of Organic Chemistry, American Chemical Society, 2017, 82 (6), pp.3311-3316. ⟨10.1021/acs.joc.7b00085⟩
Journal of Organic Chemistry, American Chemical Society, 2017, 82 (6), pp.3311-3316. ⟨10.1021/acs.joc.7b00085⟩
International audience; 4-Fluoropyrazoles are accessible in a single step from readily available aldehyde-derived N-alkylhydrazones through double C−H fluoroalkylation with tribromofluoromethane (CBr 3 F). RuCl 2 (PPh 3) 3 has been proven to be the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b893e17988fb87eaf861de3fd58a4dd4
https://hal.archives-ouvertes.fr/hal-02944776
https://hal.archives-ouvertes.fr/hal-02944776
Publikováno v:
ChemInform. 47
The copper-catalyzed azomethine trifluoromethylation of ketone-derived hydrazones with Togni′s hypervalent iodine(III)-CF3 reagent is described. The reaction gives rise to quaternary α-trifluoromethyl diazenes under mild conditions and is proposed