Reduction of [(C 5 Me 5 ) 2 Mo 2 O 5 ] and [(C 5 Me 5 ) 2 Mo 2 O 4 ] in Methanol/Water/Trifluoroacetate Solutions Investigated by Combined On‐Line Electrochemistry/Electrospray‐Ionization Mass Spectrometry

Autor: Jenny Gun, Alexandre Modestov, Ovadia Lev, Rinaldo Poli

Publikováno v: European Journal of Inorganic Chemistry. 2003:2264-2272

Complexes [Cp*2Mo2O5 ]( Cp* =η 5 -C5Me5) and [Cp*2Mo2O4] were investigated by combined on-line electrochemical (EC) reduction and electrospray-ionization mass spectrometry (ESI-MS) techniques in a trifluoroacetic acid buffered water/ methanol soluti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3b26a79a432eb7a6f18d255886bf3de3
https://doi.org/10.1002/ejic.200200627

Results and Perspectives of High Oxidation State Organomolybdenum Chemistry in Water

Autor: Edmond Collange, Funda Demirhan, Jenny Gun, Ovadia Lev, Alexandre Modestov, Rinaldo Poli, Philippe Richard, Dirk Saurenz

Publikováno v: ChemInform. 35

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f84e78bb5e2260a799d2ad0573505567
https://doi.org/10.1002/chin.200418255

High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5

Autor: Jenny Gun, Ovadia Lev, Funda Demirhan, Rinaldo Poli, Alexandre Modestov, Philippe Richard

Publikováno v: Journal of the Chemical Society Dalton Transactions
Journal of the Chemical Society Dalton Transactions, Royal Society of Chemistry, The, 2002, pp.2109-2111. ⟨10.1039/B203583A⟩
Scopus-Elsevier

International audience; Reduction of Cp*2Mo2O5 by zinc/CF3CO2H in MeOH–H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF3)3]+ and [Zn2(O2CCF3)6]2− ions after crystallisation from THF–Et2O.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c39d6e27cbaf07a3ba8c368a5d60bcb6
https://doi.org/10.1039/b203583a