Zobrazeno 1 - 10
of 77
pro vyhledávání: '"Alexander T. Radosevich"'
Publikováno v:
Journal of the American Chemical Society. 144(47)
Hydride transfer catalysis is shown to be enabled by the nonspectator reactivity of a transition metal-bound low-symmetry tricoordinate phosphorus ligand. Complex
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d4e8c1e70811172d1d55aa3e6a76506
https://pubmed.ncbi.nlm.nih.gov/36378626
https://pubmed.ncbi.nlm.nih.gov/36378626
Two-Site O–H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand
Publikováno v:
Journal of the American Chemical Society. 144:20243-20248
The synthesis and reactivity of an ambiphilic iridium complex IrCl(PPh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9cfd9a7465cf2bfe386b147aad7294f
https://doi.org/10.1021/jacs.2c10087
https://doi.org/10.1021/jacs.2c10087
Publikováno v:
J Am Chem Soc
A catalytic approach to intercept the transient HNO for a chemoselective primary amination of arylboronic acids is reported. A phosphetane-based catalyst operating within P(III)/P(V)=O redox cycling is shown to capture HNO, generated in situ by Nef d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5392a241ff4153877b8aa9d6c2f75588
https://doi.org/10.1021/jacs.2c02922
https://doi.org/10.1021/jacs.2c02922
Publikováno v:
J Am Chem Soc
An organophosphorus-catalyzed C–N bond-forming reductive coupling of nitroalkanes with arylboronic acids and esters is reported. The method shows excellent chemoselectivity for the nitro/boronic acid substrate pair, allowing synthesis of N-(hetero)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b42a28f9b33de53ae002ac97ef3baad3
https://doi.org/10.1021/jacs.2c01487
https://doi.org/10.1021/jacs.2c01487
Publikováno v:
Journal of the American Chemical Society.
A synthetic method for the reductive transformation of nitroarenes into
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2c50f7b4904d4ad08177222523c19d54
https://pubmed.ncbi.nlm.nih.gov/36562776
https://pubmed.ncbi.nlm.nih.gov/36562776
Publikováno v:
J Am Chem Soc
An organophosphorus-catalyzed method for the synthesis of unsymmetrical hydrazines by cross-selective intermolecular N–N reductive coupling is reported. This method employs a small ring phosphacycle (phosphetane) catalyst together with hydrosilane
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1873144c7bef01015505cc73e5302c3
https://doi.org/10.1021/jacs.1c07272
https://doi.org/10.1021/jacs.1c07272
Publikováno v:
J Am Chem Soc
A growing number of organopnictogen redox catalytic methods have emerged-especially within the past 10 years-that leverage the plentiful reversible two-electron redox chemistry within Group 15. The goal of this Perspective is to provide readers the c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a059983dee8774e14b8a06b632efca5a
https://doi.org/10.1021/jacs.0c12816
https://doi.org/10.1021/jacs.0c12816
Publikováno v:
Organometallics. 40:2785-2791
The design and synthesis of a nontrigonal phosphorus(III) triamide (2) bearing a peripheral ethylene bridge is described. By comparison to a compound lacking the ethylene bridge (1, (P{N[o-NMe-C6H4...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a46ec30e4468085a639f888bdbdebafd
https://doi.org/10.1021/acs.organomet.0c00750
https://doi.org/10.1021/acs.organomet.0c00750
Publikováno v:
Chem. 7:1420-1422
The installation of –CF3 or –CF2H groups into compounds can impact important biologically relevant properties. In a recent paper published in Nature, McNally, Paton, and co-workers introduce novel phosphine-based reagents that allow for the conve
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::60012f8facd0ada9026a6c53a7f82bea
https://doi.org/10.1016/j.chempr.2021.05.011
https://doi.org/10.1016/j.chempr.2021.05.011
Autor:
Alexander T. Radosevich, Soohyun Lim
Publikováno v:
Journal of the American Chemical Society. 142:16188-16193
A synthetic cycle for aryl C–F substitution comprising oxidative addition, ligand metathesis, and reductive elimination at a Cs-symmetric phosphorus triamide (1, P{N[o-NMe-C6H4]2}) is reported. Rea...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2888bd6678f9f351eb2bf70ef54c35ab
https://doi.org/10.1021/jacs.0c07580
https://doi.org/10.1021/jacs.0c07580