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pro vyhledávání: '"Alexander S. Dunn"'
Autor:
Alexander S. Dunn
Publikováno v:
Polymer International. 30:547-550
Evidence suggesting that the ultimate latex particles formed in the emulsion polymerisation of styrene are formed by the coalescence of unstable primary particles appears incompatible with the usual assumption that latex particles are predominantly n
Autor:
Alexander S. Dunn
Publikováno v:
ACS Symposium Series ISBN: 9780841223059
Polymer Latexes: Preparation, Characterization, and Applications
Polymer Latexes: Preparation, Characterization, and Applications
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c6ef963858a3b8054a03983138fbc816
https://doi.org/10.1021/bk-1992-0492.ch004
https://doi.org/10.1021/bk-1992-0492.ch004
Autor:
Uma S. Satpathy, Alexander S. Dunn
Publikováno v:
British Polymer Journal. 20:521-524
Contrary to an earlier report, monomers (e.g.p-tert-butylstyrene and octadecyl methacrylate) which are less soluble in water than styrene have been found to polymerise in emulsion using persulphate initiation. At 60°C, the order of the Interval II p
Publikováno v:
Journal of Dispersion Science and Technology. 2:175-182
Although a large number of methods are available for the determination of critical micelle concentrations many of these cannot be applied to the highest members of homologous series which are insufficiently soluble in water. The number of latex parti
Publikováno v:
British Polymer Journal. 10:137-140
Gardon's revision of the Smith-Ewart theory of emulsion polymerisation makes it possible to calculate the average particle size of the latex produced from the conditions used for the polymerisation at least for monomers with a low monomer transfer co
Autor:
Alexander S. Dunn
Publikováno v:
European Polymer Journal. 25:691-694
Although it has been generally accepted for the past 45 years that the latex particles which are the principal locus of the emulsion polymerization reaction are nucleated from monomer solubilized in emulsifier micelles, conclusive evidence to support
Autor:
Alexander S. Dunn
Publikováno v:
Die Makromolekulare Chemie. 10:1-9
Coalescence of latex particles has generally been assumed to be negligible in emulsion polymerisations although limited coalescence has been shown to determine the number of latex particles formed in the emulsion polymerisation of the more water-solu
Autor:
Ziad F.M. Said, Alexander S. Dunn
Publikováno v:
Polymer. 23:1172-1176
Using concentrations below that required to coagulate the latex, the effects of the addition of potassium chloride on the emulsion polymerization of styrene have been investigated. When potassium decanoate (an emulsifier with a high critical micelle
Autor:
Alexander S. Dunn, L. C.-H. Chong
Publikováno v:
British Polymer Journal. 2:49-59
The problem of particle formation in aqueous solutions of vinyl acetate is treated according to the Deryaguin-Landau-Verwey-Overbeek (D.L.V.O.) theory of the stability of lyophobic colloids. In the absence of surfactants, polymer particles are stabil
Autor:
Alexander S. Dunn, W.A.-G Al-Shahib
Publikováno v:
Polymer. 21:429-431
Oil-soluble initiators can produce rates of emulsion polymerization similar to those obtained with the water-soluble initiators which are normally used. Although radicals are generated in pairs in the oil phase, escape of a radical to the aqueous pha