Zobrazeno 1 - 10
of 110
pro vyhledávání: '"Alexander M, Spokoyny"'
Autor:
Sangmin Kim, Joseph W. Treacy, Yessica A. Nelson, Jordan A. M. Gonzalez, Milan Gembicky, K. N. Houk, Alexander M. Spokoyny
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-9 (2023)
Electrophilic borylation of sterically hindered arenes is a challenging transformation. Here, authors report a metal-free electrophilic C–H borylation of hindered arenes using a boron cluster reagent producing valuable aryl boronic esters.
Externí odkaz:
https://doaj.org/article/20db6fc58f9041f78d960fd9cf9b6f43
Autor:
Yueying Wang, Alexander M. Spokoyny
Publikováno v:
ACS Central Science, Vol 8, Iss 3, Pp 309-311 (2022)
Externí odkaz:
https://doaj.org/article/0684b47ce8264b23883d034530e4f4c1
Autor:
Kierstyn P. Anderson, Peter I. Djurovich, Victoria P. Rubio, Aimee Liang, Alexander M. Spokoyny
Publikováno v:
Inorganic Chemistry. 61:15051-15057
Autor:
Hayden R. Montgomery, Marco S. Messina, Evan A. Doud, Alexander M. Spokoyny, Heather D. Maynard
Publikováno v:
Bioconjugate Chemistry. 33:1536-1542
Autor:
Hayden R, Montgomery, Marco S, Messina, Evan A, Doud, Alexander M, Spokoyny, Heather D, Maynard
Publikováno v:
Bioconjug Chem
Bioconjugation techniques for biomolecule-polymer conjugation are numerous, however, slow kinetics and steric challenges generally necessitate excess reagents or long reactions times. Organometallic transformations are known to circumvent these issue
Publikováno v:
Org Lett
The (18)F-labeling of unprotected peptides and sugars with a Au(III)-[(18)F]fluoroaryl complex is reported. The chemoselective method generates (18)F-labeled S-aryl bioconjugates in an aqueous environment in 15 min with high radiochemical yields and
Autor:
Harrison A. Mills, Christopher G. Jones, Kierstyn P. Anderson, Austin D. Ready, Peter I. Djurovich, Saeed I. Khan, J. Nathan Hohman, Hosea M. Nelson, Alexander M. Spokoyny
Publikováno v:
Chemistry of Materials. 34:6933-6943
Herein, we report the use of sterically invariant carborane-based chalcogenols, containing exopolyhedral B–Se or B–S bonds, as ligands for the formation of photoluminescent copper(I)-based metal–organic chalcogenolate assemblies (MOCHAs). We sh
Publikováno v:
Organic Letters. 24:5132-5136
Autor:
Kierstyn P. Anderson, Ash Sueh Hua, John B. Plumley, Austin D. Ready, Arnold L. Rheingold, Thomas L. Peng, Peter I. Djurovich, Christopher Kerestes, Neil A. Snyder, Andrew Andrews, Justin R. Caram, Alexander M. Spokoyny
Publikováno v:
Dalton Transactions. 51:9223-9228
The dynamic photoluminescence properties, and potential quenching mechanisms, of anti-B18H22, 4,4′-Br2-anti-B18H20, and 4,4′-I2-anti-B18H20 are investigated in solution and polymer films.
Autor:
Austin D. Ready, Shona M. Becwar, Dahee Jung, Anna Kallistova, Emily Schueller, Kierstyn P. Anderson, Rebecca Kubena, Ram Seshadri, Bradley F. Chmelka, Alexander M. Spokoyny
Publikováno v:
Dalton Transactions. 51:11547-11557
We report the synthesis and characterization of a 2D coordination polymer composed of a dianionic perhydroxylated boron cluster, [B12(OH)122−], coordinated to Zn(ii)—the first example of a transition metal-coordinated [B12(OH)12]2− compound.