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Autor:
Scott W. Gordon-Wylie, Brian L. Claus, Scott P. Sellers, Colin P. Horwitz, Alexander J. Marzec, José M. Workman, Gordon T. Yee, Brenda J. Conklin, Yan Leychkis, George R. Clark, Terrence J. Collins, Clifford E. F. Rickard
Publikováno v:
Chemistry - A European Journal. 4:2173-2181
Long-lived organic cation radical species, [1I]−and [2I]−, are formed when bimetallic CoIII or VV(O) complexes of a new binucleating ligand are oxidized by one electron. The VV(O) complex, [2I]−, has a total spin, ST, of 1/2, while the robust C