Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Alexander, Virovets"'
Autor:
Marcel Bamberg, Thomas Gasevic, Michael Bolte, Alexander Virovets, Hans-Wolfram Lerner, Stefan Grimme, Markus Bursch, Matthias Wagner
Publikováno v:
Journal of the American Chemical Society 145(20), 11440-11448 (2023). doi:10.1021/jacs.3c03270
Journal of the American Chemical Society 145(20), 11440 - 11448 (2023). doi:10.1021/jacs.3c03270
Silafulleranes with endohedral Cl$^−$ ions are a unique,scarcely explored class of structurally well-defined silicon clustersand host-guest comple
Silafulleranes with endohedral Cl$^−$ ions are a unique,scarcely explored class of structurally well-defined silicon clustersand host-guest comple
Autor:
Benedikt Köstler, Hyunwoo Bae, Jannik Gilmer, Alexander Virovets, Hans-Wolfram Lerner, Philipp Albert, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemical Communications. 59:716-719
The mixed Si5Ge heterocycle (SiCl2)5(GeMe2) and its Cl− diadduct were synthesized in a highly selective fashion. The assembly mechanism was investigated to explain why precisely one GeMe2 group is incorporated, and reactivity studies were performed
Autor:
Jannik Gilmer, Timo Trageser, Luis Čaić, Alexander Virovets, Michael Bolte, Hans-Wolfram Lerner, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemical Science. 14:4589-4596
9-Borafluorene-based diboranes and silylboranes spontaneously add to CC or CC bonds. Despite their different charge and bond polarization, key orbital interactions of substrate activation are identical for both valence isoelectronic derivatives
Autor:
Sven E. Prey, Jannik Gilmer, Samira V. Teichmann, Luis Čaić, Mischa Wenisch, Michael Bolte, Alexander Virovets, Hans-Wolfram Lerner, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemical Science. 14:5316-5322
9,10-Diboratatriptycene dianions were synthesized via [4 + 2] cycloaddition between 9,10-dihydro-9,10-diboraanthracene dianions and benzyne. We show bridgehead chlorination, Me2S-adduct formation, and photorearrangement to diborabenzo[a]fluoranthenes
Autor:
Benedikt Köstler, Jannik Gilmer, Michael Bolte, Alexander Virovets, Hans-Wolfram Lerner, Philipp Albert, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemical Communications. 59:2295-2298
Two heteroadamantanes with a Si6Sn4 cluster core were prepared in one step synthesis from Me2SnCl2 and Si2Cl6/Cl−. The corresponding Si6Ge4 heteroadamantane was selectively methylated at all four SiCl3 substituents, while both SiCl2 groups remained
Publikováno v:
CrystEngComm. 24:7118-7124
Before decaying under X-rays, a single crystal of Ta-based supramolecule suffers a solid-to-solid transformation with unusual ascend of crystallographic symmetry.
Autor:
Omar Ouadoudi, Tanja Kaehler, Enes Görkem Çevik, Michael Bolte, Berthold Stöger, Alexander Virovets, Hans-Wolfram Lerner, Matthias Wagner
Publikováno v:
Dalton Transactions. 51:13195-13198
Regioselectively di- and tetrabrominated (B,O)2-perylenes were prepared and used in Stille-type couplings to afford highly luminescent alkynylated derivatives.
Autor:
Marcel Bamberg, Thomas Gasevic, Michael Bolte, Alexander Virovets, Hans-Wolfram Lerner, Stefan Grimme, Markus Bursch, Matthias Wagner
Publikováno v:
Chemical communications 59(48), 7459-7462 (2023). doi:10.1039/D3CC02142D
Chemical communications 59(48), 7459 - 7462 (2023). doi:10.1039/D3CC02142D
Starting from the perhydrogenated silafullerane [$n$Bu$_4$N][Cl@Si$_{20}$(SiH$_3$)$_{12}$H$_8$], treatment with BBr$_3$ leads to partially and exhaustively brominated clu
Starting from the perhydrogenated silafullerane [$n$Bu$_4$N][Cl@Si$_{20}$(SiH$_3$)$_{12}$H$_8$], treatment with BBr$_3$ leads to partially and exhaustively brominated clu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d392580e1213f43822bb0596192860cd
https://bib-pubdb1.desy.de/record/586214
https://bib-pubdb1.desy.de/record/586214
Autor:
Benedikt, Köstler, Hyunwoo, Bae, Jannik, Gilmer, Alexander, Virovets, Hans-Wolfram, Lerner, Philipp, Albert, Felipe, Fantuzzi, Matthias, Wagner
Publikováno v:
Chemical communications (Cambridge, England).
The Cl
A Hydride‐Substituted Homoleptic Silylborate: How Similar is it to its Diborane(6)‐Dianion Isostere?
Autor:
Jannik Gilmer, Michael Bolte, Alexander Virovets, Hans‐Wolfram Lerner, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemistry – A European Journal. 29
The B-nucleophilic 9H-9-borafluorene dianion reacts with 9-chloro-9-silafluorene to afford air- and moisture-stable silylborate salts M[Ar