Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Alex A. Cantrill"'
Publikováno v:
Tetrahedron. 62:3694-3703
The aza-Darzens (‘ADZ’) reactions of N-diphenylphosphinyl (‘N-Dpp’) imines with chiral enolates derived from N-bromoacetyl 2S-2,10-camphorsultam proceed in generally good yield to give N-diphenylphosphinyl aziridinoyl sultams. However, the st
Publikováno v:
Tetrahedron. 62:3681-3693
The aza-Darzens (‘ADZ’) reactions of N-diphenylphosphinyl (‘N-Dpp’) imines with chiral enolates derived from oxazolidinones and camphorsultam have been studied. Whilst oxazolidinone enolates reacted poorly in terms of aziridination, the use o
Publikováno v:
Tetrahedron. 54:2181-2208
Monochiral N -Diphenyphosphinyl aziridines ( ‘N- Dpp aziridines’ ) may efficiently be prepared from monochiral 2-aminoalcohols. Such aziridines undergo ring-opening reaction with a variety of nucleophiles in good yield. Dephosphinylation is accom
Publikováno v:
Tetrahedron Letters. 35:3159-3162
The improved preparation of N-diphenylphosphinoylaziridines is facilitated by the leaving group ability of the diphenylphosphinate anion
Publikováno v:
ChemInform. 25
Autor:
Lee D. Hall, Helen M. I. Osborn, Joseph B. Sweeney, Ashley N. Jarvis, Jenny Raphy, Alex A. Cantrill
Publikováno v:
ChemInform. 28
The aza-Darzens reaction of the chiral enolate derived from bromoacetylcamphorsultam 1 with N-(diphenyl-phosphinyl)aryl- and tert-butyl-methanimines proceeds in good yield to give cis-N-(diphenylphosphinyl)aziridinylcarbonyl sultams with high de. Mon
Publikováno v:
Synlett. 1996:847-849
Autor:
Joseph B. Sweeney, Alex A. Cantrill
Publikováno v:
ChemInform. 34
N,O-bis(diphenylphosphinyl)-2-(hydroxymethyl)aziridine (‘DiDpp’, 1) is efficiently prepared from 2-aminoethane-1,3-diol: this activated aziridine undergoes two sequential reactions with copper(I)-modified Grignard reagents, yielding α-branched N
Autor:
Ashley N. Jarvis, Alex A. Cantrill, Jenny Raphy, Lee D. Hall, Joseph B. Sweeney, Helen M. I. Osborn
Publikováno v:
Chemical Communications. :2631
The aza-Darzens reaction of the chiral enolate derived from bromoacetylcamphorsultam 1 with N-(diphenyl-phosphinyl)aryl- and tert-butyl-methanimines proceeds in good yield to give cis-N-(diphenylphosphinyl)aziridinylcarbonyl sultams with high de. Mon