Post-synthetic efficient functionalization of polyaniline with phosphorus-containing groups. Effect of phosphorus on electrochemical properties

Autor: Diego Cazorla-Amorós, Javier Quílez-Bermejo, Emilio San-Fabián, Emilia Morallón, Daniel Grau-Marín, Alessio Ghisolfi

Publikováno v: RUA. Repositorio Institucional de la Universidad de Alicante
Universidad de Alicante (UA)

P-postmodified polyaniline was obtained by reacting phosphorus trichloride (PCl3) and chlorodiphenylphosphine (PPh2Cl) and polyaniline (PANI), under mild conditions. The reaction was found to be very selective, as only the imine groups were involved

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::977315a65f68d48abc1a7c4278b3b635
https://doi.org/10.1016/j.eurpolymj.2019.07.048

Changes in molecular film metallicity with minor modifications of the constitutive quinonoid zwitterions

Autor: Pierre Braunstein, Minghui Yuan, Peter A. Dowben, Iori Tanabe, Bernard Doudin, Lucie Routaboul, Juan A. Colón Santana, Alessio Ghisolfi, William Serrano Garcia

Publikováno v: RSC Advances. 7:21906-21917

Molecular films of quinonoid zwitterions, of the general formula C6H2([horiz bar, triple dot above]O)2([horiz bar, triple dot above]NHR)2, have been shown to display electronic properties highly dependent on the nature of the N-substituent R when dep

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a625cb372c1ec66344d77863f7150a85
https://doi.org/10.1039/c7ra01597f

Functionalized TiO 2 Nanorods on a Microcantilever for the Detection of Organophosphorus Chemical Agents in Air

Autor: Valérie Keller, Alessio Ghisolfi, Denis Spitzer, Urelle Biapo, Geoffrey Gerer, Thomas Cottineau

Publikováno v: ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces, Washington, D.C. : American Chemical Society, 2019, 11 (38), pp.35122-35131. ⟨10.1021/acsami.9b11504⟩
ACS Applied Materials & Interfaces, 2019, 11 (38), pp.35122-35131. ⟨10.1021/acsami.9b11504⟩

International audience; We report the fabrication of nanostructured microcantilevers employed as sensors for the detection of organophosphorus (OPs) vapors. These micromechanical sensors are prepared using a two-step procedure first optimized on a si

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e8e9615c7b10dacf36b05a5daf8f237c
https://hal.archives-ouvertes.fr/hal-03093840

Multilayer graphene functionalized through thermal 1,3-dipolar cycloadditions with imino esters: a versatile platform for supported ligands in catalysis

Autor: José M. Sansano, Marcos Ferrándiz-Saperas, Carmen Nájera, Diego Cazorla-Amorós, Alessio Ghisolfi

Publikováno v: RUA. Repositorio Institucional de la Universidad de Alicante
Universidad de Alicante (UA)

Multilayer graphene (MLG), obtained by mild sonication of graphite in NMP or pyridine, was fully characterized via atomic force microscopy (AFM), transmission electron microscopy (TEM), Raman spectroscopy and X-ray photoemission spectroscopy (XPS). T

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a0302c37dcf26c91121fe2b2bbefb46
http://hdl.handle.net/10045/93687

Adsorption phenomena of cubane-type tetranuclear Ni(II) complexes with neutral, thioether-functionalized ligands on Au(111)

Autor: Kirill Yu. Monakhov, Pierre Braunstein, Frank Matthes, Volkmar Heß, Claus M. Schneider, Paul Kögerler, Claire Besson, Daniel E. Bürgler, Alessio Ghisolfi

Publikováno v: Surface science 641, 210-215 (2015). doi:10.1016/j.susc.2015.06.026

The controlled and intact deposition of molecules with specific properties onto surfaces is an emergent field impacting a wide range of applications including catalysis, molecular electronics, and quantum information processing. One strategy is to in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3ed034281afa7ed9872139baf0254460
https://doi.org/10.1016/j.susc.2015.06.026