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From oximes to tertiary alcohols in water, at room temperature and under air: a hybrid one-pot tandem assembly of enzymatic deoximation and RLi/RMgX reagents

Autor: Davide Arnodo, Marina Ramos-Martín, Luciana Cicco, Vito Capriati, Nicolás Ríos-Lombardía, Javier González-Sabín, Alejandro Presa Soto, Joaquín García-Álvarez

Publikováno v: Organic & Biomolecular Chemistry. 21:4414-4421

The design of a hybrid one-pot tandem protocol through the combination of biodeoximations (promoted by laccase from Trametes versicolor) and s-block polar organometallics (RLi/RMgX) in aqueous media, at room temperature and under air is reported.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3788c8b5b9f79e7bccc015b28fd6bece
https://doi.org/10.1039/d3ob00285c

Cylindrical Micelles by the Self-Assembly of Crystalline-b-Coil Polyphosphazene-b-P2VP Block Copolymers. Stabilization of Gold Nanoparticles

Autor: Maria de los Angeles Cortes, Raquel de la Campa, Maria Luisa Valenzuela, Carlos Díaz, Gabino A. Carriedo, Alejandro Presa Soto

Publikováno v: Molecules, Vol 24, Iss 9, p 1772 (2019)

During the last number of years a variety of crystallization-driven self-assembly (CDSA) processes based on semicrystalline block copolymers have been developed to prepare a number of different nanomorphologies in solution (micelles). We herein prese

Externí odkaz: https://doaj.org/article/70e4a9de0cc74cb3bfcf54120b04f490

Combination of organocatalytic oxidation of alcohols and organolithium chemistry (RLi) in aqueous media, at room temperature and under aerobic conditions

Autor: Alejandro Presa Soto, Eva Hevia, Joaquín García-Álvarez, Francisco Morís, David Elorriaga, María J. Rodríguez-Álvarez, Javier González-Sabín, Nicolás Ríos-Lombardía

Publikováno v: Chemical Communications. 56:8932-8935

A tandem protocol to access tertiary alcohols has been developed which combines the organocatalytic oxidation of secondary alcohols to ketones followed by their chemoselective addition by several RLi reagents. Reactions take place at room temperature

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f231edc12419a3b44a4f3892a2a0c5c4
https://doi.org/10.1039/d0cc03768k

Advancing Air‐ and Moisture‐Compatible s‐Block Organometallic Chemistry Using Sustainable Solvents

Autor: Sergio E. García-Garrido, Joaquín García-Álvarez, Alejandro Presa Soto, Eva Hevia

Publikováno v: García-Garrido, Sergio E.; Presa Soto, Alejandro; Hevia, Eva; García-Álvarez, Joaquín (2021). Advancing Air- and Moisture-Compatible s-Block Organometallic Chemistry Using Sustainable Solvents. European journal of inorganic chemistry, 2021(31), pp. 3116-3130. Wiley-VCH 10.1002/ejic.202100347
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RUO. Repositorio Institucional de la Universidad de Oviedo
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S.E.G.-G. and J.G.A thank the Spanish MINECO and MIC (Project PID2020-113473GB-I00). J.G.-A. thanks: i) the Fundación BBVA for the award of a “Beca Leonardo a Investigadores y Creadores Culturales 2017”; and ii) PhosAgro/UNESCO/IUPAC for the awa

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::654e4db3663263ad4b30884e5e48c24a
https://boris.unibe.ch/164708/1/Euro_J_of_Inorganic_Chem_-_2021_-_Garc_a_u2010Garrido_-_Advancing_Air_u2010_and_Moisture_u2010Compatible_s_u2010Block_Organometallic_Chemistry.pdf