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Radical Mediated Decarboxylation of Amino Acids via Photochemical Carbonyl Sulfide (COS) Elimination
Publikováno v:
Molecules, Vol 29, Iss 7, p 1465 (2024)
Herein, we present the first examples of amino acid decarboxylation via photochemically activated carbonyl sulfide (COS) elimination of the corresponding thioacids. This method offers a mild approach for the decarboxylation of amino acids, furnishing
Externí odkaz:
https://doaj.org/article/4d2b100beaac429cb961ba0c6042a941
Publikováno v:
Chemical Society reviews. 50(19)
Nature harnesses the unique properties of cysteinyl radical intermediates for a diverse range of essential biological transformations including DNA biosynthesis and repair, metabolism, and biological photochemistry. In parallel, the synthetic accessi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3895071296030e3602554935f52ac506
https://pubmed.ncbi.nlm.nih.gov/34397045
https://pubmed.ncbi.nlm.nih.gov/34397045