Synthesis, Characterization and Biological Activity of Novel Cu(II) Complexes of 6-Methyl-2-Oxo-1,2-Dihydroquinoline-3-Carbaldehyde-4n-Substituted Thiosemicarbazones

Autor: Eswaran Ramachandran, Valentina Gandin, Roberta Bertani, Paolo Sgarbossa, Karuppannan Natarajan, Nattamai S. P. Bhuvanesh, Alfonso Venzo, Alfonso Zoleo, Mirto Mozzon, Alessandro Dolmella, Alberto Albinati, Carlo Castellano, Nuno Reis Conceição, M. Fátima C. Guedes da Silva, Cristina Marzano

Publikováno v: Molecules, Vol 25, Iss 8, p 1868 (2020)

Three new 6-methyl-2-oxo-1,2-dihydroquinoline-3-carbaldehyde-thiosemicarbazones-N-4-substituted pro-ligands and their Cu(II) complexes (1, -NH2; 2, -NHMe; 3, -NHEt) have been prepared and characterized. In both the X-ray structures of 1 and 3, two cr

Externí odkaz: https://doaj.org/article/e2febf980cf640a88a97abe80fbae655

Dynamics of bound states of dihydrogen at Cu(I) and Cu(II) species coordinated near one and two zeolite framework aluminium atoms: A combined sorption, INS, IR and DFT study

Autor: Alberto Albinati, Konstantin Hadjiivanov, Jacques Ollivier, Nikola Drenchev, Peter A. Georgiev, Tobias Unruh

Publikováno v: International journal of hydrogen energy 46 (2021): 26897–26914. doi:10.1016/j.ijhydene.2021.05.166
info:cnr-pdr/source/autori:Georgiev P.A.; Drenchev N.; Hadjiivanov K.I.; Ollivier J.; Unruh T.; Albinati A./titolo:Dynamics of bound states of dihydrogen at Cu(I) and Cu(II) species coordinated near one and two zeolite framework aluminium atoms: A combined sorption, INS, IR and DFT study/doi:10.1016%2Fj.ijhydene.2021.05.166/rivista:International journal of hydrogen energy/anno:2021/pagina_da:26897/pagina_a:26914/intervallo_pagine:26897–26914/volume:46
'International Journal of Hydrogen Energy ', vol: 46, pages: 26897-26914 (2021)

Ambient conditions sorption isotherms of dihydrogen in a series of various levels of Cu-exchanged ZSM-5 zeolites, with two different Si/Al ratios, namely 11.5 and 25, show the presence of different amount of Cu centres able to strongly bind H2. Altho

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::201af814e09bbedbc6a2b36b651563d6
https://www.sciencedirect.com/science/article/pii/S0360319921020188

Open Metal Sites in the Metal–Organic Framework CPO-27-Cu: Detection of Regular and Defect Copper Species by CO and NO Probe Molecules

Autor: Alberto Albinati, Mali H. Rosnes, Pascal D. C. Dietzel, Peter A. Georgiev, Nikola Drenchev, Konstantin Hadjiivanov

Publikováno v: The Journal of Physical Chemistry C. 122:17238-17249

The open copper metal sites in CPO-27-Cu were studied by means of IR spectroscopy of adsorbed CO and NO, and density functional theory calculations. Very low Lewis acidity of the Cu2+ sites was established by CO (IR band at 2153–2149 cm–1). Varia

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::31bae5846285447d62af88e4d97eb5e2
https://doi.org/10.1021/acs.jpcc.8b04045

Correction to 'Observation of Exceptionally Strong Binding of Molecular Hydrogen in a Porous Material: Formation of an η2-H2 Complex in a Cu-Exchanged ZSM-5 Zeolite'

Autor: Alberto Albinati, Peter A. Georgiev, Jacques Ollivier, Barbara Mojet, Juergen Eckert

Publikováno v: Journal of the American Chemical Society. 143:1247-1247

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e22b005cf7c45ef72ecacee5b5545eef
https://doi.org/10.1021/jacs.0c12936

Crystal growth in gelled solution: applications to coordination polymers

Autor: Alberto Albinati, Silvia Rizzato, Marco Merlini, Fabio Beghi, Massimo Moret

Publikováno v: CrystEngComm. 18:2455-2462

Some critical issues concerning the complex synthesis and crystallization of designed coordination polymers are highlighted by using gels as diffusion media. The systematic use of gel methods in a variety of different crystallization configurations h

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00d1c6fb72e962e22dea9c760fa2b9de
https://doi.org/10.1039/c6ce00289g