Zobrazeno 1 - 10
of 277
pro vyhledávání: '"Alan R. Battersby"'
Autor:
Alan R. Battersby
Publikováno v:
CHIMIA, Vol 47, Iss 5 (1993)
Externí odkaz:
https://doaj.org/article/b99cce82a0ae449ab7ebb6ddce39e200
Autor:
Alan R. Battersby
Publikováno v:
Natural Product Reports. 17:507-526
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :879-888
5-Amino[4-13C]laevulinic acid has been synthesised for enzymic conversion into 13C-labelled precorrin-2 12a. This was incubated with an enzyme system from Propionibacterium shermanii in the presence of [4-2H2]NADH 5a and [4-2H2]NADPH 6a to yield coby
Publikováno v:
The Journal of Organic Chemistry. 63:8163-8169
Attachment of an alkyl- or arylsulfonyl group at the nitrogen atom of a pyrrole reduces the aromaticity and electron availability of the system. This is confirmed by the structure of an N-tosylated chloromethylpyrrole determined by X-ray crystallogra
Publikováno v:
Journal of the American Chemical Society. 120:1741-1746
A sequence, based on a Mitsunobu displacement at the hydroxymethyl position of deuterium-labeled, N-substituted 2-(hydroxymethyl)pyrroles, is reported as a general procedure to determine the ability of the N-substituent to deactivate the heterocycle.
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :1509-1518
Autor:
Robert N. Woodhouse, David R. Julian, Alan R. Battersby, Gilbert Hardy, Robert Ramage, Edward McDonald, Alan C. Barker
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :2989-2994
Labelled samples are prepared of demecolcine 3, colchicine 4, N-formyl-N-deacetylcolchicine 6 and N-deacetylcolchicine 7, the last depending on a new method for its preparation from colchicine. Incorporation experiments with these compounds and with
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :1519-1530
The proposed intermediacy of the spiro-pyrrolenine 1 for the biosynthesis of uroporphyrinogen III has focussed attention on its synthesis. Several different approaches to close analogues of this compound are explored, including (a) the synthesis of a
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :2995-3002
Autor:
N. Patrick J. Stamford, Paul M. Petersen, Finian J. Leeper, Alan R. Battersby, Craig J. Hawker
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :1531-1540
The proposed intermediacy of the spiro-system 1 for the biosynthesis of uroporphyrinogen III has focused attention on its synthesis. In this paper the approach that is explored is to carry a dihydropyrrole through the entire synthesis with the intent