Mass spectral and theoretical characterisation of non-symmetric Mo(V) dithiolene complexes

Autor: Hélène Lavanant, Alain Mallard, Nicole Sellier, Corine Simonnet-Jégat, Catherine Fressigné, Francis Sécheresse, Rémi Dessapt

Publikováno v: International Journal of Mass Spectrometry
International Journal of Mass Spectrometry, Elsevier, 2005, 243 (3), pp.205-214. ⟨10.1016/j.ijms.2005.03.002⟩

The gas phase fragmentations of a family of three anionic complexes of molybdenum(V), [Mo2(O)2(μ-S)2(η2-S2)2]2−, [Mo2(O)2(μ-S)2(η2-S2) (η2-S2C2H2)]2−, [Mo2(O)2(μ-S)2(η2-S2)(η2-S2C2(C6H5)2)]2− were studied as a function of the collision

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7b0f988ca8eb6abae71a2b0994cee853
https://doi.org/10.1016/j.ijms.2005.03.002

Synthesis and X-ray characterization of nickel(II) arsenatotungstate complexes: isolation of an intermediate leading to the formation of a sandwich-type polyoxometalate

Autor: Jérôme Marrot, Gilbert Herve, Pierre Mialane, Alain Mallard

Publikováno v: Inorganica Chimica Acta. 328:81-86

The nickel arsenatotungstate K10[As2W19(H2O){Ni(H2O)}2O67]·18H2O (1) has been synthesized. Due to its instability in water, attempts to obtain crystals of 1 suitable for X-ray diffraction have failed. The stabilization of the [As2W19(H2O){Ni(H2O)}2O

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d70411396f87f7db08bba69e064070ee
https://doi.org/10.1016/s0020-1693(01)00689-2

Reactivity of tetrathiometalates with alkynes. Synthesis and characterisation of dithiolene complexes of Mo, W, and V by ESMS and XRD

Autor: Hélène Lavanant, Francis Sécheresse, Corine Simonnet-Jégat, Alain Mallard, Jérôme Marrot

Publikováno v: Transition Metal Chemistry
Transition Metal Chemistry, Springer Verlag, 2008, 33 (2), pp.143-152. ⟨10.1007/s11243-007-9005-3⟩

The reaction of DMA (C2(CO2Me)2) with MoS 4 2− , WS 4 2− , and VS 4 3− led to six dithiolene compounds. (NEt4)2[Mo2(X)2(μ-S) 2(η2-S2C2(CO2Me)2)2] 1, (X = O or S), (NEt4)2[V(η2-S2C2(CO2Me)2)3] 2a, (NEt4)2[V(O)(η2-S2C2(CO2Me)2)2] 2b, (NEt4)2[

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4ab3238a9cf6ad2d009036b57f241241
https://hal-normandie-univ.archives-ouvertes.fr/hal-02351596

Solid-State and Solution Studies of {Ln n (SiW 11 O 39 )} Polyoxoanions: An Example of Building Block Condensation Dependent on the Nature of the Rare Earth

Autor: Pierre Mialane, Laurent Lisnard, Elisabeth Antic-Fidancev, Alain Mallard, Jérôme Marrot, Francis Sécheresse, Daniel Vivien, P. Aschehoug

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 2003, 42 (6), pp.2102-2108. ⟨10.1021/ic020486f⟩
Inorganic Chemistry, American Chemical Society, 2003, 42 (6), pp.2102-2108. ⟨10.1021/ic020486f⟩

The reactivity of the [α-SiW 1 1 O 3 9 ] 8 - monovacant polyoxometalate with lanthanide has been investigated for four different trivalent rare-earth cations (Ln = Nd I I I , Eu I I I , Gd I I I , Yb I I I ). The crystal structures of KCs 4 [Yb(α-S

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5f7e6207241608814af7adce152ff8fe
https://hal.science/hal-02326231

[e-PMo12O36(OH)4{La(H2O)4}4]5+: The First e-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reduced α-PMo12O40 Isomer

Autor: Laurent Lisnard, Francis Sécheresse, Anne Dolbecq, Pierre Mialane, Alain Mallard, Jérôme Marrot

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2002, 41 (13), pp.2398. ⟨10.1002/1521-3773(20020703)41:133.0.CO;2-A⟩

International audience

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ef0b1374b6d4ebd496b3bb406474148b
https://hal.archives-ouvertes.fr/hal-02326189