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Publikováno v:
Chemistry – A European Journal. 24:18043-18051
The reactions of the three triplet ground state arylcarbenes diphenylcarbene 1, fluorenylidene 2, and dibenzocycloheptadienylidene 3 with the Lewis acids H2 O, ICF3 , and BF3 were studied under the conditions of matrix isolation. H2 O was selected as
Autor:
Mika Maehara, Akshay Hemant Raut, Masashi Tsuge, Yuan-Pern Lee, Wolfram Sander, Joel Mieres-Perez, Enrique Mendez-Vega
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 24(70)
The hydrogenation reactions of diphenylcarbene 1, fluorenylidene 2, and dibenzocycloheptadienylidene 3 were investigated in solid H2 and D2 matrices and in H2 - and D2 -doped argon matrices at cryogenic temperatures. The reactivity of the carbenes to