Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Akira Tanushi"'
Publikováno v:
Journal of the American Chemical Society. 144(47)
Hydride transfer catalysis is shown to be enabled by the nonspectator reactivity of a transition metal-bound low-symmetry tricoordinate phosphorus ligand. Complex
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d4e8c1e70811172d1d55aa3e6a76506
https://pubmed.ncbi.nlm.nih.gov/36378626
https://pubmed.ncbi.nlm.nih.gov/36378626
Two-Site O–H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand
Publikováno v:
Journal of the American Chemical Society. 144:20243-20248
The synthesis and reactivity of an ambiphilic iridium complex IrCl(PPh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9cfd9a7465cf2bfe386b147aad7294f
https://doi.org/10.1021/jacs.2c10087
https://doi.org/10.1021/jacs.2c10087
Autor:
Scott R. Daly, Akira Tanushi, Sean M. McCarthy, Kyounghoon Lee, Kyle D. Spielvogel, Jason M. Keith, Courtney M. Donahue, Alexander T. Radosevich, Anastasia V. Blake, Daniel Kim, Sydney M. Loria
Publikováno v:
PMC
Angew Chem Int Ed Engl
Angew Chem Int Ed Engl
Constraining σ3-P compounds in nontrigonal, entatic geometries has proven to be an effective strategy for promoting biphilic oxidative addition reactions more typical of transition metals. Although qualitative descriptions of the impact of structure
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1ed045d956877f82d3a4a809694337d
https://doi.org/10.1002/anie.201901779
https://doi.org/10.1002/anie.201901779
Autor:
Yasutaka Kitagawa, Moe Tominaga, Tetsuro Kusamoto, Masayoshi Nakano, Shun Kimura, Akira Tanushi, Hiroshi Nishihara
Publikováno v:
The Journal of Physical Chemistry C. 123:4417-4423
Some organic radicals violate the Aufbau principle and have unique electronic structures in which the energy level of the singly occupied molecular orbital (SOMO) is formally lower than that of the highest occupied molecular orbital (HOMO). We synthe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d1ffc5103e720b539e9e4e26b56ce432
https://doi.org/10.1021/acs.jpcc.8b08574
https://doi.org/10.1021/acs.jpcc.8b08574
Publikováno v:
J Am Chem Soc
Insertion of a tricoordinate phosphorus ligand into late metal–carbon bonds is reported. Metalation of a P^P-chelating ligand (L1), composed of a nontrigonal phosphorous(1) triamide moiety (i.e. P(N(o-N(Ar)C(6)H(4))(2)) tethered by a phenylene link
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::184be523198f6f36bf0f004e92f55af9
https://europepmc.org/articles/PMC7806272/
https://europepmc.org/articles/PMC7806272/
Autor:
Kosuke Tsukada, Satoshi Kashiwagi, Wataru Katagiri, Akira Tanushi, Hak Soo Choi, Geon Hui Lee
Publikováno v:
Journal of Biomedical Optics
Significance: Photobiomodulation is a well-established therapeutic modality. However, the mechanism of action is poorly understood, due to lack of research in the causal relationship between the near-infrared (NIR) light irradiation and its specific
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c9ce7d66e54f12bba206dc544dd51af0
https://doi.org/10.1117/1.jbo.25.3.036003
https://doi.org/10.1117/1.jbo.25.3.036003
Autor:
Alexander T. Radosevich, Akira Tanushi
Publikováno v:
Journal of the American Chemical Society. 140(26)
The synthesis and reactivity of an NPN-chelating ligand containing a nontrigonal phosphorous triamide center (L1 = P(N(o-N(2-pyridyl)C6H4)2) is reported. Metalation of L1 with RuCl2(PPh3)3 gives RuCl2(PPh3)(L1) (2). By contrast, metalation of L1 with
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1222c3e6660e7fdbd6524f97c94c32d2
https://pubmed.ncbi.nlm.nih.gov/29923715
https://pubmed.ncbi.nlm.nih.gov/29923715
Publikováno v:
Inorganic Chemistry. 54:4186-4188
Novel metal complexes M(hfac)2(PyBTM)2 [M = Cu(II), Zn(II); hfac = hexafluoroacetylacetonato; PyBTM = (3,5-dichloro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl radical] were prepared. Both hexacoordinated complexes had elongated octahedral geometry, i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::36f231f73bb277fc2663e8565e3e281e
https://doi.org/10.1021/acs.inorgchem.5b00499
https://doi.org/10.1021/acs.inorgchem.5b00499
Publikováno v:
Journal of the American Chemical Society; 5/27/2015, Vol. 137 Issue 20, p6448-6451, 4p
Publikováno v:
Inorganic Chemistry; 5/4/2015, Vol. 54 Issue 9, p4186-4188, 3p