Výsledky vyhledávání - "Akanksha Santosh Deshpande"

Ruthenium-Catalyzed Directed C(3)–H Olefination of N-Acetyl-1,2-dihydroisoquinolines: A Method to Achieve C3-Olefinated Isoquinolines

Autor: Nandkishor Prakash Khot, Manmohan Kapur, Akanksha Santosh Deshpande, Riki Das

Publikováno v: Synthesis. 51:2515-2522

A unique approach to achieve regioselective C(3)–H olefination of isoquinolines under ruthenium-catalyzed conditions has been developed. The acetyl group of N-acetyl-1,2-dihydroisoquinoline acts as a directing group for this C–H olefination strat

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7d8d695123d7c469f2d3245c13dd4a45
https://doi.org/10.1055/s-0037-1611807

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Catalyst Control in Switching the Site Selectivity of C-H Olefinations of 1,2-Dihydroquinolines: An Approach to Positional-Selective Functionalization of Quinolines

Autor: Nandkishor Prakash Khot, Manmohan Kapur, Akanksha Santosh Deshpande, Riki Das

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 26(4)

A unique approach to achieve site-selective C-H olefinations exclusively at the C-3- or C-8-positions in the quinoline framework has been developed by catalyst control. Distal C(3)-H functionalization is achieved by using palladium catalysis, whereas

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b13c6370f8e4193dc18552c223e7724f
https://pubmed.ncbi.nlm.nih.gov/31625636

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