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Autor:
Santiago Reinoso, Beñat Artetxe, Leire San Felices, Estibaliz Ruiz-Bilbao, Leticia Fernández-Navarro, Ana San José Wéry, Aitor Nunes-Collado, J.M. Gutiérrez-Zorrilla
Publikováno v:
Inorganic chemistry. 60(8)
The unprecedented heptavanadate cluster has been isolated from reactions between trisalkoxide ligands and vanadate in water at pH = 2 as a series of alkylammonium [HxV7O18(H2O)((OCH2)3CR)](4-x)- salts (1-3, R = CH2OH; 4, R = CH3). Their structures ha