Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Aiichiro Ori"'
Publikováno v:
Chemistry Letters. 25:301-302
A calix[4]arene bearing three amide groups (composing a lanthanide binding site) and one sensitizer (phenacyl group) bearing an (o-boronylphenyl)methylaminomethyl group (acting as a sugar-binding site) was synthesized. The energy-transfer to Eu3+ was
Publikováno v:
Chemical Communications. :407
F– and saccharides which feature specific affinity with the bornic acid group can be detected visually by the redox reaction between ferrocenylboronic acid derivatives and dyes with the appropriate redox potentials.
Autor:
Seiji Shinkai, Aiichiro Ori
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1771
A chiral ferrocenylboronic acid 1 bearing an intramolecular tertiary amine binds saccharides at ca. pH 7, the complexation event, which can be conveniently detected by an electrochemical method, shows chiral discrimination for certain linear sacchari
Publikováno v:
Chemistry Letters. 15:13-16
Hydrolysis of optically pure 1-alkenyl-2-sulfonyloxy-1-propanone acetals afforded optically and geometrically pure title compounds via stereospecific 1,2-rearrangement of alkenyl group.
Publikováno v:
Chemistry Letters. 16:1259-1262
Chiral sesquiterpenes, (+)-Davanone and (+)-Artemone, were synthesized via anti-selective epoxidation and iodo-cyclization by the use of (S)-ethyl lactate as a chiral source.
Publikováno v:
Bulletin of the Chemical Society of Japan. 60:1027-1036
(S)-1-Aryl-2-sulfonyloxy-1-alkanone acetals, prepared from natural ethyl (S)-lactate or (S)-valine (chiral sources) by the use of a Grignard reaction, were rearranged under hydrolytic conditions in the presence of a base to give (S)-2-arylalkanoic es
Publikováno v:
Chemischer Informationsdienst. 17
Hydrolysis of optically pure 1-alkenyl-2-sulfonyloxy-1-propanone acetals afforded optically and geometrically pure title compounds via stereospecific 1,2-rearrangement of alkenyl group.
Publikováno v:
ChemInform. 18
Title compounds were treated with EtAlCl2 or TiC3OPri and t-butyl hydroperoxide (TBHP) at −78 °C, followed by K2CO3 to give anti-epoxide, which reacted with LiAlH4 at γ-position.
Publikováno v:
ChemInform. 18
(S)-1-Aryl-2-sulfonyloxy-1-alkanone acetals, prepared from natural ethyl (S)-lactate or (S)-valine (chiral sources) by the use of a Grignard reaction, were rearranged under hydrolytic conditions in the presence of a base to give (S)-2-arylalkanoic es