Coordinatively Unsaturated Amidotitanocene Cations with Inverted σ and π Bond Strengths: Controlled Release of Aminyl Radicals and Hydrogenation/Dehydrogenation Catalysis

Autor: Hélène Cattey, Pierre Le Gendre, E. Daiann Sosa Carrizo, Adrien T. Normand, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Quentin Bonnin, Tereza Edlová

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2021, ⟨10.1002/chem.202103487⟩

Cationic amidotitanocene complexes [Cp2 Ti(NPhAr)][B(C6 F5 )4 ] (Cp=η5 -C5 H5 ; Ar=phenyl (1 a), p-tolyl (1 b), p-anisyl (1 c)) were isolated. The bonding situation was studied by DFT (Density Functional Theory) using EDA-NOCV (Energy Decomposition

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::050629d4205bd044d33b3390898c93d4
https://doi.org/10.1002/chem.202103487

The Taming of Redox‐Labile Phosphidotitanocene Cations

Autor: Charles H. Devillers, Paul Fleurat-Lessard, Adrien T. Normand, Cédric Balan, Gerhard Erker, Philippe Richard, Gerald Kehr, Stéphane Brandès, Pierre Le Gendre, Quentin Bonnin

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, 2019, 25 (11), pp.2803-2815. ⟨10.1002/chem.201805430⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2019, 25 (11), pp.2803-2815. ⟨10.1002/chem.201805430⟩

International audience; Tame d0 phosphidotitanocene cations stabilized with a pendant tertiary phosphane arm are reported. These compounds were obtained by one-electron oxidation of d1 precursors with [Cp2Fe][BPh4]. The electronic structure of these

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::15a9834b7f4a62bd31f3fb924b4fa4fd
https://doi.org/10.1002/chem.201805430

Synthetic Endeavors toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and Steric Properties

Autor: Constantin G. Daniliuc, Gerald Kehr, Cédric Balan, Pierre Le Gendre, Adrien T. Normand, Gerhard Erker, Philippe Richard

Publikováno v: Organometallics. 34:2000-2011

A new family of cationic Ti complexes 4′ with a pendant phosphine of general formula [CpCpPTiOAr][BPh4] (Cp = η5-C5H5; CpP = η5-C5H4(CMe2)PR2) has been prepared in four steps from 6,6-dimethylfulvene. These complexes were designed to behave as Ti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1cf9d0a6a8e9b2eee27f9db25ce99c65
https://doi.org/10.1021/acs.organomet.5b00250

Insertion Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated Lewis Pair Territory

Autor: Birgit Wibbeling, Gerald Kehr, Adrien T. Normand, Constantin G. Daniliuc, Gerhard Erker, Pierre Le Gendre

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2016, 22 (12), pp.4285-4293. 〈http://onlinelibrary.wiley.com/doi/10.1002/chem.201504792/full〉. 〈10.1002/chem.201504792〉
Chemistry-A European Journal, Wiley-VCH Verlag, 2016, 22 (12), pp.4285-4293. ⟨10.1002/chem.201504792⟩

International audience; Neutral phosphidozirconocene complexes [Cp2Zr(PR2)Me] (Cp=cyclopentadienyl; 1a: R=cyclohexyl (Cy); 1b: R=mesityl (Mes); 1c: R=tBu) undergo insertion into the Zr-P bond by non-enolisable carbonyl building blocks (O=CRR), such a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::05e9585bf22843f77ce221f56cbc5d32
https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01400485

CHAPTER 9. NHC–Palladium Complexes in Catalysis

Autor: Adrien T. Normand, Kingsley J. Cavell, David S. McGuinness

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c583ada9e024c476435306773fb6c186
https://doi.org/10.1039/9781782626817-00336