Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Adrian Y. Houghton"'
Autor:
Tom Autrey, Adrian Y. Houghton
Publikováno v:
The Journal of Physical Chemistry A. 121:8785-8790
The mechanism of H2 heterolysis by the frustrated Lewis pair of B(C6F5)3 and P(mes)3 was investigated by isothermal reaction calorimetry in the temperature range from 30 to 90 °C. The experimental heat curves were modeled in Berkeley Madonna to obta
Autor:
S. Thomas Autrey, Mark E. Bowden, Kriston P. Brooks, Adrian Y. Houghton, Abhijeet J. Karkamkar
Publikováno v:
Journal of Power Sources. 324:170-178
Chemical hydrogen storage (CHS) materials are a high-storage-density alternative to the gaseous compressed hydrogen currently used to provide hydrogen for fuel cell vehicles. One of the challenges of CHS materials is addressing the energy barriers re
Publikováno v:
Chem. Commun.. 50:1295-1298
The perfluorinated boraindene was synthesized and fully characterized. Both computational and crystallographic data show that is antiaromatic. Compound was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechan
Autor:
Andrea E. Kirby, Adrian Y. Houghton, Robert McDonald, D.J. Harrison, Lisa Rosenberg, Miranda K. Skjel
Publikováno v:
Organic Letters. 12:376-379
B(C(6)F(5))(3)-catalyzed bis(hydrosilylation) of alpha-diketones can give high diastereomeric excess of either meso/anti (small silanes and disilane reagents) or dl/syn (bulky silanes) silyl-protected 1,2-diols. This easily tuned diastereoselectivity
Autor:
Adrian Y. Houghton, Heikki M. Tuononen, Akseli Mansikkamäki, Warren E. Piers, Juha Hurmalainen
Publikováno v:
Nature chemistry. 6(11)
Perfluorarylborane Lewis acids catalyse the addition of silicon-hydrogen bonds across C=C, C=N and C=O double bonds. This 'metal-free' hydrosilylation has been proposed to occur via borane activation of the silane Si-H bond, rather than through class
Autor:
D.J. Harrison, Miranda K. Skjel, Andrea E. Kirby, Adrian Y. Houghton, Lisa Rosenberg, Robert McDonald
Publikováno v:
ChemInform. 41
B(C6F5)3-catalyzed bis(hydrosilylation) of α-diketones can give high diastereomeric excess of either meso/anti (small silanes and disilane reagents) or dl/syn (bulky silanes) silyl-protected 1,2-diols. This easily tuned diastereoselectivity is ratio
Autor:
Cheng Fan, Jason L. Dutton, Lauren G. Mercier, Qiao Wu, Adrian Y. Houghton, Warren E. Piers, Masood Parvez, Aiko Fukazawa
Publikováno v:
Chemical Science. 3:1814
The highly Lewis acidic perfluoropentaphenylborole forms a stable, isolable adduct with the weak Lewis base carbon monoxide. A similar adduct with the unfluorinated borole is observed at low temperature, but this adduct undergoes reaction involving i
Autor:
Miranda K. Skjel, Adrian Y. Houghton, Andrea E. Kirby, Daniel J. Harrison, Robert McDonald, Lisa Rosenberg
Publikováno v:
Organic Letters; Jan2010, Vol. 12 Issue 2, p376-379, 4p
Publikováno v:
Chemical Communications; 2014, Vol. 50 Issue 11, p1295-1298, 4p
Publikováno v:
Chemical Communications; 2014, Vol. 50 Issue 11, p1275-1283, 9p