Zobrazeno 1 - 10
of 39
pro vyhledávání: '"Adriaan De Vries"'
Autor:
Mary E. Neubert, Carol A. Hanlon, Michael J. Zawaski, Adriaan De Vries, Theresa Louise Benyo, Patricia J. Wildman
Publikováno v:
Molecular Crystals and Liquid Crystals. 145:111-157
The effect of replacingk an alkoxy (Y = OR') with an acyloxy (Y=OCOR') group on the phenolic end of the esters: on their mesomorphic properties has been studied. These esters were prepared by esterification of 4-acyloxyphenols with the appropriate ac
Autor:
Henry A. Ellis, Adriaan De Vries
Publikováno v:
Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics. 163:133-138
X-ray diffraction is used to study structural changes associated with thermotropic phase transitions in a homologous series of even-chain-length lead(II) carboxylates from hexanoate to octadecanoate. For homologues above lead(II) dodecanoate, a lamel
Autor:
Adriaan De Vries
Publikováno v:
Molecular Crystals and Liquid Crystals. 63:215-229
A systematic classification of thermotropic smectic phases has been developed, with fourteen different phase types. First, the assumption is made that inall smectic phases the molecular packing within the layers is based on a herringbone arrangement
Autor:
Mary E. Neubert, Adriaan De Vries
Publikováno v:
Molecular Crystals and Liquid Crystals. 145:1-15
Microscopic studies of the nematic phase in the 4-n-alkoxybenzoic acids have shown that the nematic-to-isotropic transition has a range ≥ 0.9° which is larger than the 0.2–0.3° range usually seen for this transition. This wide range was also ob
Autor:
Adriaan de Vries
Publikováno v:
The Journal of Chemical Physics. 70:2705-2709
On the basis of evidence in the literature, it is concluded that the basic molecular packing underlying all smectic structures is a herringbone arrangement of the molecular planes with an orthogonal lattice of the molecular centers. Starting from thi
Publikováno v:
The Journal of Chemical Physics. 74:4048-4052
The biaxial smectic‐B‐type phase of 4‐n‐pentylbenzenethio‐4′‐n‐tetradecyloxybenzoate (14S5) has been studied along with its uniaxial smectic‐l B phase. The results are interpreted in terms of identical layer structures in both phase
Publikováno v:
Molecular Crystals and Liquid Crystals. 49:143-152
Even though the average molecular direction in smectic A phases is perpendicular to the smectic planes, most molecules in these phases have rather large tilt angles because the orientational order parameter S in all smectic A phases is significantly
Publikováno v:
Molecular Crystals and Liquid Crystals. 139:299-320
The effect of inserting a ketone group in th α-positon of the alkyl chain on the phenolic end of 4,4'-disubstituted phenylbenzoates and di-(4'-subsituted phenyl)-trnas-cyclohexane-1, 4-dicarboxylates on mesomorphic properties as compared to those pr
Autor:
Adriaan De Vries
Publikováno v:
Molecular Crystals and Liquid Crystals. 49:19-25
The most important experimental differences between solid crystals and liquid crystals with three-dimensional order are suggested to be that liquid crystals with optically active molecules form twisted structures, whereas solid crystals do not, and t
Autor:
Adriaan De Vries
Publikováno v:
Molecular Crystals and Liquid Crystals. 41:27-31
Experimental evidence is presented indicating that there are two distinctly different kinds of smectic C to smectic A transitions. The first type is second order with zero tilt in both phases, the second type is first order with a non-zero tilt angle