Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Aditya Ramesh Sachin"'
Publikováno v:
Results in Chemistry, Vol 7, Iss , Pp 101498- (2024)
The complexation behavior of phosphate, phosphine oxide, and phosphoramide ligands with Th(IV) is investigated at the Density Functional Theory (DFT) level. Employing Energy Decomposition Analysis (EDA), the study reveals significant contributions of
Externí odkaz:
https://doaj.org/article/317259f6139f4b60a16626f3a47379ca
Autor:
Puchakayala Rajani, Aditya Ramesh Sachin, Sivaraman Nagarajan, Cherukuri Venkata Siva Brahmananda Rao, Gopinadhanpillai Gopakumar
Publikováno v:
Inorganic Chemistry. 61:13047-13057
The electronic structure and complexation behavior of methyl-substituted phosphinic acids with U(VI) and Pu(IV) were explored by applying quantum chemical methods. In contrast to Ingold's classification, our results indicate that the methyl group is
Autor:
Gopinadhanpillai Gopakumar, N. Sivaraman, C. V. S. Brahmananda Rao, G. Jegan, A. Suresh, B. Sreenivasulu, Aditya Ramesh Sachin
Publikováno v:
Inorganica Chimica Acta. 525:120496
The strong basic nature and amenability of three nitrogen subunits of hexaalkyl phosphoramides (HalP) make them as potential extractants for the recovery of actinides by solvent extraction. The six alkyl groups present in the molecule improve the sel