Zobrazeno 1 - 6 of 6 pro vyhledávání: '"Adelheid Demeyer"'
1
Symmetric and asymmetric proton transfer from heptane and octane radical cations to heptane molecules in γ-irradiated n-C7H16–n-C8H18–2-C6H13Cl crystals: structural disorder in mixed alkane crystals
Autor: Jan Ceulemans, Adelheid Demeyer
Publikováno v: J. Chem. Soc., Perkin Trans. 2. :1875-1881
A study has been made of the isomeric composition of secondary chloroheptanes formed upon γ-irradiation at 77 K and subsequent melting of heptane containing 1 mol% 2-chlorohexane and various concentrations of octane. It is observed that the relative
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3bff838e5bdd3b0b21f5aec378bc7095
https://doi.org/10.1039/b206335m
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2
Carbon−Hydrogen vs Carbon−Carbon Protonation in the Proton Transfer from Alkane Radical Cations to Alkane Molecules. A Study in γ-Irradiated CCl3F/Decane at 77 K
Autor: Adelheid Demeyer, Jan Ceulemans
Publikováno v: The Journal of Physical Chemistry A. 104:4004-4010
A study is made of the formation of the isomeric chlorodecanes, and a search is made for shorter-chain 1-chloroalkanes (5 ≤ nC ≤ 9) formed in CCl3F/decane by γ-irradiation at 77 K and subsequent me...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7751e3bce2d2da3ffdddeb70a771ed47
https://doi.org/10.1021/jp994124d
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3
Proton acceptor site selectivity in the proton transfer from heptane radical cations to decane molecules in γ-irradiated heptane/decane/1-chloroheptane crystals at 77 K
Autor: Jan Ceulemans, Adelheid Demeyer, Lutgart Slabbinck
Publikováno v: Journal of the Chemical Society, Perkin Transactions 2. :2241-2247
A study is made of the yield and isomeric composition of chlorodecanes formed by γ-irradiation of heptane/decane/1-chloroheptane crystals at 77 K and subsequent warming. It is observed that in such systems 2-chlorodecane is predominantly formed with
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::47192086d94b68515f1c3e02268f61f2
https://doi.org/10.1039/b004829l
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4
Intrinsic Acceptor Site Selectivity in the Proton Transfer from Alkane Radical Cations to Alkane Molecules. Evidence in γ-Irradiated CCl3F/Undecane
Autor: Adelheid Demeyer, Jan Ceulemans
Publikováno v: The Journal of Physical Chemistry A. 101:3537-3541
A study is made of intrinsic acceptor site selectivity in the proton transfer from alkane radical cations to alkane molecules. The research is conducted by studying the relative degree of protonation at the various C−H bonds in undecane in irradiat
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1a695d6e05d46fcb8bc2a500bcf24ea0
https://doi.org/10.1021/jp964062g
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6
Preferential solvent-to-solute proton transfer upon ionization by .gamma.-irradiation of solid heptane/octane-d18 systems: proton transfer as an alternative process to hole transfer in irradiated solid binary alkane systems
Autor: Dominique Stienlet, Jan Ceulemans, Adelheid Demeyer
Publikováno v: The Journal of Physical Chemistry. 97:1477-1479
A study is made of the effect of added octane-dis on the ESR spectrum of heptane observed after γ-irradiation at 77 K. It is found that the presence of deuterated octane in heptane upon γ-irradiation results in a substantial increase in the relativ
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8f993976170345d40c18d3e622152b99
https://doi.org/10.1021/j100110a003
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