Výsledky vyhledávání - "Adam W. E. Stewart"

Dissecting Transmetalation Reactions at the Molecular Level: Role of the Coordinated Anion in Gas-Phase Models for the Transmetalation Step of the Hiyama Cross-Coupling Reaction

Autor: Geethika K. Weragoda, Howard Z. Ma, George N. Khairallah, Adam W. E. Stewart, Richard A. J. O'Hair, Allan J. Canty

Publikováno v: Organometallics. 40:1822-1829

Palladium-catalyzed cross-coupling protocols have become a cornerstone in organic synthesis. Here, a gas-phase model of the Hiyama cross-coupling reaction was designed to shed light on the roles of coordinated anions (fluoride versus chloride) in tra

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cd61eff1141b816893d357ff932ccc78
https://doi.org/10.1021/acs.organomet.0c00795

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Dissecting transmetalation reactions at the molecular level: C-B versus F-B bond activation in phenyltrifluoroborate silver complexes

Autor: Allan J. Canty, Richard A. J. O'Hair, Adam W. E. Stewart, Fiona L.B. Bathie

Publikováno v: Dalton transactions (Cambridge, England : 2003). 50(4)

The gas-phase unimolecular reactions of the silver(I) complex [Ag(PhBF3)2]−, formed via electrospray ionisation mass spectrometry of solutions containing the phenyltrifluoroborate salt and AgNO3, are examined. Upon collision induced dissociation (C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19c2ae33d56bdb099dd663c4bc95a5dc
https://pubmed.ncbi.nlm.nih.gov/33439189

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