Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Adam S. Berlin"'
Publikováno v:
ACS Catalysis. 5:3189-3195
Grubbs-type ruthenium-complex-mediated intramolecular alkene hydrosilylation of alkenylsilyl ethers has been developed to provide cyclic silyl ethers with high regioselectivity. This non-metathetical use of such ruthenium complexes for alkene hydrosi
Publikováno v:
European Journal of Organic Chemistry. 2014:5890-5895
A cooperative ligand-assisted, Rh-catalyzed intramolecular alkene hydrosilylation of homoallylic silyl ethers (1) was developed to provide 1,3-trans-oxasilacyclopentanes (trans-2) in a highly regio- and diastereoselective manner. The modification of
Publikováno v:
ChemInform. 46
The precursors oxasilacyclopentanes for trans-1,3-diols are synthesized in a highly regio- and diastereoselective manner by using [RhCl(BINAP)]2 as catalyst.