Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Adam L. Tenderholt"'
Publikováno v:
European Journal of Inorganic Chemistry. 2021:4066-4073
The multiredox reactivity of bioinorganic cofactors is often coupled to proton transfers. Here we investigate the structural, thermochemical, and electronic structure of ruthenium-amino/amido complexes with multi- proton-coupled electron transfer rea
Publikováno v:
Eur J Inorg Chem
The multiredox reactivity of bioinorganic cofactors is often coupled to proton transfers. Here we investigate the structural, thermochemical, and electronic structure of ruthenium-amino/amido complexes with multi- proton-coupled electron transfer rea
Publikováno v:
European Journal of Inorganic Chemistry. 2021:4042-4042
Autor:
Yang Ha, Britt Hedman, Edward I. Solomon, Richard H. Holm, Adam L. Tenderholt, Keith O. Hodgson
Publikováno v:
Journal of the American Chemical Society
Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of two complexes [Mo(IV)O(bdt)2](2-) and [Mo(VI)O2(bdt)2](2-) (bdt = benzene-1,2-dithiolate(2-))
Publikováno v:
Inorganic Chemistry. 51:3436-3442
Reaction coordinates for oxo transfer from the substrates Me(3)NO, Me(2)SO, and Me(3)PO to the biologically relevant Mo(IV) bis-dithiolene complex [Mo(OMe)(mdt)(2)](-) where mdt = 1,2-dimethyl-ethene-1,2-dithiolate(2-), and from Me(2)SO to the analog
Publikováno v:
Coordination Chemistry Reviews. 255:993-1015
The similarities and differences in the fundamental coordination chemistry of molybdenum and tungsten mainly in physiological oxidation states MIV–VI are examined in relation to the properties of enzyme sites that catalyze oxygen atom transfer reac
Autor:
Keith O. Hodgson, Jun-Jieh Wang, Richard H. Holm, Adam L. Tenderholt, Edward I. Solomon, Britt Hedman, Robert K. Szilagyi
Publikováno v:
Journal of the American Chemical Society. 132:8359-8371
Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of two Mo bis-dithiolene complexes, [Mo(OSi)(bdt)(2)](1-) and [MoO(OSi)(bdt)(2)](1-), where OSi =
Autor:
Shaun D. Wong, Yuming Xiao, Matt C. Smith, Eric J. Klinker, Caleb B. Bell, Jan Uwe Rohde, Lawrence Que, Edward I. Solomon, Stephen P. Cramer, Adam L. Tenderholt
Publikováno v:
Angewandte Chemie International Edition. 47:9071-9074
FeIV=O biomimetic model complexes have been characterized using nuclear vibrational resonance spectroscopy (NRVS). Features and systematic trends in the low energy region reflect equatorial and axial bonding differences that relate to differences in
Autor:
Caleb B. Bell, Shaun D. Wong, Yuming Xiao, Eric J. Klinker, Adam L. Tenderholt, Matt C. Smith, Jan-Uwe Rohde, Lawrence Que, Stephen P. Cramer, Edward I. Solomon
Publikováno v:
Angewandte Chemie. 120:9211-9214
Autor:
Keith O. Hodgson, Adam L. Tenderholt, Robert K. Szilagyi, Britt Hedman, Edward I. Solomon, Richard H. Holm
Publikováno v:
Inorganic Chemistry. 47:6382-6392
Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of a series of Mo tris(dithiolene) complexes, [Mo(mdt)3]z (where mdt = 1,2-dimethylethene-1,2-dit